多维刺激响应RTP微米纤维薄膜

IF 1.3 4区 材料科学 Q3 CHEMISTRY, APPLIED
Junjian Lu, Hongbin Zhong, Fei Luo
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引用次数: 0

摘要

本研究的目的是:以1,1 ':3 ',1″-terphenyl-5'-硼酸(DPP-OH)和聚乙烯醇(PVA)为原料合成DPP-BOH-PVA。通过改变DPP-OH的含量(1、2和4 Wt.%),研究了DPP-BOH-PVA的余辉寿命。用傅里叶红外变换、x射线衍射和DSC热分析对膜进行了表征。余辉寿命通过时间分辨发射衰减曲线分析进行评估。采用静电纺丝法制备了直径为5 μm的DPP-BOH-PVA-2-E纤维膜,在常温条件下余辉寿命为2.1 s (@ 535 nm)。研究了纤维薄膜随余辉发射的刺激响应特性。在聚合物合成过程中,采用DPP-OH/PVA,摩尔比为1/4,在含氢氧化铵的碱性介质中,在80℃的温度下进行改性。XRD结果表明,DPP-BOH-PVA薄膜结晶度高,是制备有机室温磷光(RTP)材料的关键。研究局限/启示反应混合物必须连续搅拌。应控制温度,防止氢氧化铵迅速蒸发。本研究为合成多维刺激响应的RTP微米纤维薄膜提供了技术信息。静电纺丝技术还可以促进RTP薄膜的大面积应用。该树脂将用于RTP纤维薄膜的多维刺激响应。静电纺丝法得到的PP-BOH-PVA-2-E纤维膜直径在5 μm范围内,余辉寿命衰减为2.1 s。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Multidimensional stimulation response RTP micron fiber thin film
Purpose The purpose of this research is as follows: DPP-BOH-PVA has been synthesized from 1,1′:3′,1″-terphenyl-5'-boronic acid (DPP-OH) and polyvinyl alcohol (PVA). The afterglow lifetime of DPP-BOH-PVA was studied by changing contents of DPP-OH (1, 2 and 4 Wt.%). These films were characterized with Fourier transform infrared, X-ray diffraction as structural analysis and DSC as thermal analysis. Afterglow lifetimes were evaluated as time-resolved emission decay profile analysis. Fiber films of DPP-BOH-PVA-2-E have been prepared by electrospinning method with the diameter of 5 μm and afterglow life time of 2.1 s (@ 535 nm) under ambient conditions. Stimulus responsive properties with afterglow emission for fiber film were investigated. Design/methodology/approach During the synthesis of the polymer, modification was carried out using DPP-OH/PVA with a molar ratio of 1/4, under an alkalinity medium with ammonium hydroxide and with a temperature of 80°C. Findings XRD results indicate that DPP-BOH-PVA film had high crystallinity, which is crucial for preparing organic room temperature phosphorescence (RTP) materials. Research limitations/implications The reaction mixture must be stirred continuously. Temperature should be controlled to prevent the rapid evaporation of ammonium hydroxide. Practical implications This study provides technical information for the synthesis of multidimensional stimulation response RTP micron fiber thin film. The electrospinning technology may also promote the applications of the large areas of RTP films. Social implications This resin will be used for the multidimensional stimulation response RTP fiber thin film. Originality/value The diameter of fiber film of PP-BOH-PVA-2-E by electrospinning method was in the range of 5 μm, and its afterglow lifetime decayed to be 2.1 s.
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来源期刊
Pigment & Resin Technology
Pigment & Resin Technology 工程技术-材料科学:膜
CiteScore
2.80
自引率
21.40%
发文量
91
审稿时长
>12 weeks
期刊介绍: The journal looks at developments in: ■Adhesives and sealants ■Curing and coatings ■Wood coatings and preservatives ■Environmentally compliant coating systems and pigments ■Inks for food packaging ■Manufacturing machinery - reactors, mills mixing and dispersing equipment, pumps ■Packaging, labeling and storage ■Plus topical features and news on materials, coatings, industry people, conferences, books and so on ■Raw materials such as pigments, solvents, resins and chemicals ■Testing equipment and procedures
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