Thomas A. Welsh, Jacquelyn G Egan, Bart Dietrich, Niamh Rafferty, Rebecca E Ginesi, James Doutch, Ralf Schweins, Emily R Draper
{"title":"氨基酸功能化对苝酰亚胺光电性能和自组装的影响","authors":"Thomas A. Welsh, Jacquelyn G Egan, Bart Dietrich, Niamh Rafferty, Rebecca E Ginesi, James Doutch, Ralf Schweins, Emily R Draper","doi":"10.1088/2515-7639/ad08d2","DOIUrl":null,"url":null,"abstract":"Abstract Here we report on ten water-soluble perylene bisimides that are functionalised with the amino acids L-alanine, L-aspartic acid, L-glutamic acid, L-phenylalanine, L-histidine, L-leucine, L-methionine, L-valine, L-tryptophan, and L-tyrosine. Reduction potentials, absoprtion and emission spectra, molar absorptivity, quantum yield, and rheology are obtained and the data interpreted for each species in aqueous solution or hydrogels in order to provide a comprehensive understanding of the subtle effects of amino acid functionalisation on the optoelectronic and supramolecular properties.","PeriodicalId":36054,"journal":{"name":"JPhys Materials","volume":"58 28","pages":"0"},"PeriodicalIF":4.9000,"publicationDate":"2023-11-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"The Effects of Amino Acid Functionalisation on the Optoelectronic Properties and Self-Assembly of Perylene Bisimides\",\"authors\":\"Thomas A. Welsh, Jacquelyn G Egan, Bart Dietrich, Niamh Rafferty, Rebecca E Ginesi, James Doutch, Ralf Schweins, Emily R Draper\",\"doi\":\"10.1088/2515-7639/ad08d2\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Abstract Here we report on ten water-soluble perylene bisimides that are functionalised with the amino acids L-alanine, L-aspartic acid, L-glutamic acid, L-phenylalanine, L-histidine, L-leucine, L-methionine, L-valine, L-tryptophan, and L-tyrosine. Reduction potentials, absoprtion and emission spectra, molar absorptivity, quantum yield, and rheology are obtained and the data interpreted for each species in aqueous solution or hydrogels in order to provide a comprehensive understanding of the subtle effects of amino acid functionalisation on the optoelectronic and supramolecular properties.\",\"PeriodicalId\":36054,\"journal\":{\"name\":\"JPhys Materials\",\"volume\":\"58 28\",\"pages\":\"0\"},\"PeriodicalIF\":4.9000,\"publicationDate\":\"2023-11-13\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"JPhys Materials\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1088/2515-7639/ad08d2\",\"RegionNum\":3,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"MATERIALS SCIENCE, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"JPhys Materials","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1088/2515-7639/ad08d2","RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"MATERIALS SCIENCE, MULTIDISCIPLINARY","Score":null,"Total":0}
The Effects of Amino Acid Functionalisation on the Optoelectronic Properties and Self-Assembly of Perylene Bisimides
Abstract Here we report on ten water-soluble perylene bisimides that are functionalised with the amino acids L-alanine, L-aspartic acid, L-glutamic acid, L-phenylalanine, L-histidine, L-leucine, L-methionine, L-valine, L-tryptophan, and L-tyrosine. Reduction potentials, absoprtion and emission spectra, molar absorptivity, quantum yield, and rheology are obtained and the data interpreted for each species in aqueous solution or hydrogels in order to provide a comprehensive understanding of the subtle effects of amino acid functionalisation on the optoelectronic and supramolecular properties.