{"title":"混合技术对气体分离混合膜理化特性的影响","authors":"Danial Qadir, Humbul Suleman, Faizan Ahmad","doi":"10.3390/gases3040009","DOIUrl":null,"url":null,"abstract":"Polymer blending has attracted considerable attention because of its ability to overcome the permeability–selectivity trade-off in gas separation applications. In this study, polysulfone (PSU)-modified cellulose acetate (CA) membranes were prepared using N-methyl-2-pyrrolidone (NMP) and tetrahydrofuran (THF) using a dry–wet phase inversion technique. The membranes were characterized using scanning electron microscopy (SEM) for morphological analysis, thermogravimetric analysis (TGA) for thermal stability, and Fourier transform infrared spectroscopy (FTIR) to identify the chemical changes on the surface of the membranes. Our analyses confirmed that the mixing method (the route chosen for preparing the casting solution for the blended membranes) significantly influences the morphological and thermal properties of the resultant membranes. The blended membranes exhibited a transition from a finger-like pore structure to a dense substructure in the presence of macrovoids. Similarly, thermal analysis confirmed the improved residual weight (up to 7%) and higher onset degradation temperature (up to 10 °C) of the synthesized membranes. Finally, spectral analysis confirmed that the blending of both polymers was physical only.","PeriodicalId":12796,"journal":{"name":"Greenhouse Gases: Science and Technology","volume":null,"pages":null},"PeriodicalIF":2.7000,"publicationDate":"2023-09-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Effect of Mixing Technique on Physico-Chemical Characteristics of Blended Membranes for Gas Separation\",\"authors\":\"Danial Qadir, Humbul Suleman, Faizan Ahmad\",\"doi\":\"10.3390/gases3040009\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Polymer blending has attracted considerable attention because of its ability to overcome the permeability–selectivity trade-off in gas separation applications. In this study, polysulfone (PSU)-modified cellulose acetate (CA) membranes were prepared using N-methyl-2-pyrrolidone (NMP) and tetrahydrofuran (THF) using a dry–wet phase inversion technique. The membranes were characterized using scanning electron microscopy (SEM) for morphological analysis, thermogravimetric analysis (TGA) for thermal stability, and Fourier transform infrared spectroscopy (FTIR) to identify the chemical changes on the surface of the membranes. Our analyses confirmed that the mixing method (the route chosen for preparing the casting solution for the blended membranes) significantly influences the morphological and thermal properties of the resultant membranes. The blended membranes exhibited a transition from a finger-like pore structure to a dense substructure in the presence of macrovoids. Similarly, thermal analysis confirmed the improved residual weight (up to 7%) and higher onset degradation temperature (up to 10 °C) of the synthesized membranes. Finally, spectral analysis confirmed that the blending of both polymers was physical only.\",\"PeriodicalId\":12796,\"journal\":{\"name\":\"Greenhouse Gases: Science and Technology\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":2.7000,\"publicationDate\":\"2023-09-26\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Greenhouse Gases: Science and Technology\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.3390/gases3040009\",\"RegionNum\":4,\"RegionCategory\":\"环境科学与生态学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"ENERGY & FUELS\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Greenhouse Gases: Science and Technology","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.3390/gases3040009","RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"ENERGY & FUELS","Score":null,"Total":0}
Effect of Mixing Technique on Physico-Chemical Characteristics of Blended Membranes for Gas Separation
Polymer blending has attracted considerable attention because of its ability to overcome the permeability–selectivity trade-off in gas separation applications. In this study, polysulfone (PSU)-modified cellulose acetate (CA) membranes were prepared using N-methyl-2-pyrrolidone (NMP) and tetrahydrofuran (THF) using a dry–wet phase inversion technique. The membranes were characterized using scanning electron microscopy (SEM) for morphological analysis, thermogravimetric analysis (TGA) for thermal stability, and Fourier transform infrared spectroscopy (FTIR) to identify the chemical changes on the surface of the membranes. Our analyses confirmed that the mixing method (the route chosen for preparing the casting solution for the blended membranes) significantly influences the morphological and thermal properties of the resultant membranes. The blended membranes exhibited a transition from a finger-like pore structure to a dense substructure in the presence of macrovoids. Similarly, thermal analysis confirmed the improved residual weight (up to 7%) and higher onset degradation temperature (up to 10 °C) of the synthesized membranes. Finally, spectral analysis confirmed that the blending of both polymers was physical only.
期刊介绍:
Greenhouse Gases: Science and Technology is a new online-only scientific journal dedicated to the management of greenhouse gases. The journal will focus on methods for carbon capture and storage (CCS), as well as utilization of carbon dioxide (CO2) as a feedstock for fuels and chemicals. GHG will also provide insight into strategies to mitigate emissions of other greenhouse gases. Significant advances will be explored in critical reviews, commentary articles and short communications of broad interest. In addition, the journal will offer analyses of relevant economic and political issues, industry developments and case studies.
Greenhouse Gases: Science and Technology is an exciting new online-only journal published as a co-operative venture of the SCI (Society of Chemical Industry) and John Wiley & Sons, Ltd