新型有机-无机杂化硼酸盐K[B5O6(OH)4][B(OH)3]2(H2O)(C10H20O5)2的合成与晶体结构

IF 0.8 4区材料科学 Q4 MATERIALS SCIENCE, CERAMICS

Glass Physics and Chemistry Pub Date : 2023-11-16 DOI:10.1134/S1087659623600485

V. A. Yukhno, D. O. Charkin, S. N. Volkov, L. S. Manelis, A. N. Gosteva, S. M. Aksenov, R. S. Bubnova

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引用次数: 0

摘要

从水溶液中制备了一种新型有机无机杂化硼酸盐K[B5O6(OH)4][B(OH)3]2(H2O)(C10H20O5)2(1)晶体，并用单晶x射线衍射和红外光谱对其进行了表征。1为三斜(a = 10.1567(4)， b = 11.9941(6)， c = 17.1893(9) Å， α = 75.280(4)， β = 79.406(4)， γ = 88.531(4)°，V = 1990.270369 Å3, SG P-1;R1 = 0.058)。它的结构包含[K(C10H20O5)2]+基团，这些基团作为由\({{{\text{B}}}_{{\text{5}}}}{{{\text{O}}}_{{\text{6}}}}\left( {{\text{OH}}} \right)_{4}^{ - }\)阴离子和中性B(OH)3分子组成的无机部分的“疏水”模板。

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Synthesis and Crystal Structure of a Novel Organo-Inorganic Hybrid Borate, K[B5O6(OH)4][B(OH)3]2(H2O)(C10H20O5)2

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Synthesis and Crystal Structure of a Novel Organo-Inorganic Hybrid Borate, K[B5O6(OH)4][B(OH)3]2(H2O)(C10H20O5)2

Crystals of a novel hybrid organo-inorganic borate, K[B₅O₆(OH)₄][B(OH)₃]₂(H₂O)(C₁₀H₂₀O₅)₂ (1), were obtained from aqueous solutions and characterized by single-crystal X-ray diffraction and IR spectroscopy. 1 is triclinic (a = 10.1567(4), b = 11.9941(6), c = 17.1893(9) Å, α = 75.280(4), β = 79.406(4), γ = 88.531(4)°, V = 1990.270369 Å³, SG P-1; R₁ = 0.058). Its structure contains [K(C₁₀H₂₀O₅)₂]⁺ groups which behave as “hydrophobic” templates for the inorganic part comprised of \({{{\text{B}}}_{{\text{5}}}}{{{\text{O}}}_{{\text{6}}}}\left( {{\text{OH}}} \right)_{4}^{ - }\) anions and neutral B(OH)₃ molecules.

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来源期刊

Glass Physics and Chemistry 工程技术-材料科学：硅酸盐

CiteScore

1.20

自引率

14.30%

发文量

审稿时长

6-12 weeks

期刊介绍： Glass Physics and Chemistry presents results of research on the inorganic and physical chemistry of glass, ceramics, nanoparticles, nanocomposites, and high-temperature oxides and coatings. The journal welcomes manuscripts from all countries in the English or Russian language.