用于制造薄壁高强度结构的环氧粘合剂的选择性固化方法

T. Man'ko, K. Siedachova, Khrystyna Kozis
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引用次数: 0

摘要

目的为了改善环氧树脂组合物的物理力学特性,降低能耗、成本,减少生产面积,以及保护环境,对于聚合物复合材料制成的硬化薄壁结构,有必要选择最合理的固化方法。方法制备尺寸为10х10х10 mm的环氧粘合剂ЭДТ-10+УП606/2(1%)样品,分别采用对流加热、红外加热和指定模式的选择性红外加热进行硬化。红外加热是由三个卤素白炽灯КГТ-220-1000-1内部和使用盐过滤器提供。提出了三种工艺的复合硬化模式。结果表明,采用选择性红外加热的方法可以获得最高的显微硬度。金相研究表明,聚合物获得了致密的结构,硬化程度高,约为97%。对ЭДТ-10环氧胶结剂硬化试样进行力学试验。测定了显微硬度后,发现ЭДТ-10粘结剂在选择性硬化过程中的显微硬度分别为34,57 kgf/mm2,红外加热- 30,85 kgf/mm2,对流加热- 29,61 kgf/mm2。为了从红外发射器获得最大的比功率,使用了盐滤光片,其中发射能量的主要部分落在波长(2,8 - 3,2)•10-6 nm上。这种技术允许您选择必要的频带。环氧组分样品硬化实验结果表明,与对流加热至少7小时、红外加热2小时30分钟相比,红外加热选择法硬化过程耗时1小时15分钟。选择性方法在整个待处理表面上提供均匀的温度分布,从而确保高物理和机械特性。结论在实验研究的基础上,采用助选方法对环氧树脂固化的PCM硬化样品进行了红外光谱分析,与传统的对流加热硬化相比,环氧树脂固化的PCM硬化样品具有较高的机械耐久性和致密的结构。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
SELECTIVE METHOD OF CURING EPOXY BINDERS FOR THE CREATION OF THIN-WALLED HIGH- STRENGTH STRUCTURES
Purpose To improve the physical and mechanical characteristics of the epoxy composition, reduce energy consump-tion, cost, reduce production areas, as well as protect the environment, for the hardening thin-walled structures made of polymer composite materials, it is necessary to choose the most rational method for curing polymer composite materials. Methodology The prepared samples of the epoxy binder ЭДТ-10+УП606/2(1%) with a size of 10х10х10 mm, were hardened by convective, IR heating, and selective IR heating according to specified modes. IR heating is provided by unit with three halogen incandescent lamps type КГТ-220-1000-1 inside and using a salt filter. The mode of composition hardening according to three technologies has been developed. Findings The results of measurements of the cured samples showed that the highest microhardness was achieved using selective IR heating. Metallographic studies has shown that polymer obtained a compact structure with a high degree of hardening, approximately 97%. Hardened samples of ЭДТ-10 epoxy binder were subjected to mechanical tests. Having determined the microhardness, it was found that during the selective hardening of the ЭДТ-10 binder, the microhardness was 34,57 kgf/mm2, IR heating - 30,85 kgf/mm2, convective heating – 29,61 kgf/mm2. Originality To obtain the maximum specific power from the IR emitter, salt filters were used, in which the main part of the emitted energy fell on the wavelength (2,8 – 3,2)•10-6 м. This technique allows you to select the necessary frequency bands. Practicalvalue The results of epoxy composition samples hardening experiment showed that the hardening process by the IR heating selective method takes 1 hour and 15 minutes, in contrast to convective heating which requires at least 7 hours and IR heating with 2 hours and 30 minutes. The selective method provides a uniform temperature distribution over the entire surface to be treated, which ensures high physical and mechanical characteristics. Conclusions On the basis of experimental researches with help selective method IR of hardening samples from PCM have been received on the basis of epoxy binding which possess high mechanical durability and compact structure in comparison with a composition which hardening a traditional convection heating.
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