用羊脂生产生物柴油

Selva Ilavarasi Panneerselvam, L. R. Miranda
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引用次数: 9

摘要

目前,除了水力发电和核能外,世界上的能源需求都是通过石油化工、天然气和煤炭等不可再生资源来满足的。柴油燃料在发展中国家的工业经济中具有重要作用,用于运输农业和工业产品。工业世界和家庭部门的高能源需求以及由于广泛使用矿物燃料而造成的污染问题,使得有必要从比传统能源对环境影响较小的可再生能源中开发替代能源。因此,替代能源必须来自一种燃料,这种燃料必须在技术上可行、经济上具有竞争力、环境上可接受并易于获得。一种可能的替代方案是使用植物来源的油,这被称为生物柴油。它是一种可生物降解、无毒的国内资源,从而减轻了对石油燃料进口的依赖。同时具有较低的CO、颗粒物和未燃烃排放等燃烧排放特征。生物柴油燃烧产生的二氧化碳可以通过光合作用循环利用,从而最大限度地减少生物柴油燃烧对温室效应的影响。虽然植物油的热值与柴油相似,但其在直喷柴油机中的使用受到粘度等物理特性的限制,其粘度约为柴油的10倍,从而造成燃料雾化不良,燃烧不完全,喷油器上积碳,润滑油中的燃料积聚导致严重的发动机污垢。这些问题可以通过使用合适的溶剂稀释、乳化、热解和酯交换等处理来缓解。酯交换反应是一种常见的公认的化学反应,其中线性单羟基醇与植物油(脂肪酸的甘油三酯)在催化剂的存在下发生反应。它实际上是用另一个醇取代酯中的醇基。碱催化酯交换反应被认为是所有从生鲜油中生产生物柴油的方法中最好的。在本研究中,我们尝试将羊脂肪作为低成本、可持续的生物柴油原料。考察了催化剂用量、温度、甲醇用量、反应时间等工艺参数对生物柴油生产的影响。获得了50g羊肉脂肪的最佳加工工艺条件。在最佳条件下,羊肉脂肪甲酯得率为93.2%。对燃料的密度、运动粘度、酸值、浊点、碘值、皂化值、倾点、十六烷值等性能进行了评价。研究发现,羊脂非常适合用于生产具有推荐燃料性能的生物柴油。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Biodiesel production from mutton tallow
Presently the world's energy needs are met through non-renewable resources such as petrochemicals, natural gas and coal, with the exception of Hydroelectricity and nuclear energy. Diesel fuels have the essential function in the industrial economy of a developing country and are used for transport of agricultural and industrial goods. The high energy demand in the industrial world as well as in the domestic sector and pollution problems caused due to the widespread use of fossil fuel make it necessary to develop the alternate energy from renewable sources with lesser environmental impact than traditional one. Thus, an alternate energy must be from a fuel which must be technically feasible, economically competitive, environmentally acceptable and readily available. One possible alternative is the use of oils of plant origin, which is termed as Biodiesel. It is a biodegradable, non-toxic, domestic resource thereby relieving reliance on petroleum fuel imports. It also has more favorable combustion emission profile, such as low emission of CO, particulate matter and unburned Hydrocarbon. CO2 produced by combustion of Biodiesel can be recycled by photosynthesis, thereby minimizing the impact of Biodiesel combustion on the green house effect. Though the heating value of Vegetable oil is similar to that of diesel fuel, their use in Direct Injection diesel engine is restricted by the physical properties like viscosity which is approximately 10 times higher than diesel fuel thereby creating poor fuel atomization, incomplete combustion, carbon deposition on the injector, fuel buildup in the lubricant oils resulting in serious engine fouling. These problems may be alleviated by employing various treatments like dilution with a suitable solvent, emulsification, pyrolysis and Transesterification. Transesterification is a common well established chemical reaction in which linear monohydroxyl alcohols reacts with vegetable oils which are triglycerides of fatty acids, in the presence of a catalyst. It is actually the replacement of alcohol group from an ester by another alcohol. Alkali catalyzed transesterification is considered to be the best amongst all methods available for the production of biodiesel from fresh oil. In the present investigation an attempt has been made to use mutton fat as low cost sustainable potential feed stock for biodiesel production. Effect of various process parameters such as amount of catalyst, temperature, amount of methanol and reaction time on biodiesel production was investigated. The optimal conditions for processing 50 g of mutton fat were obtained. Under optimal conditions, the yield of mutton fat methyl esters was 93.2%. The fuel properties like Density, kinematic viscosity, acid value, cloud point, iodine value, saponification value, pour point and cetane value was estimated. Mutton fat was found to be highly suitable to produce biodiesel with recommend fuel properties.
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