掺钼单斜钒酸铋的合成与结构

International Conference on Oxide Materials for Electronic Engineering - fabrication, properties and applications (OMEE-2014) Pub Date : 2014-05-26 DOI:10.1109/OMEE.2014.6912338

K. Bychkov, K. Terebilenko, V. Baumer, N. Slobodyanik

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引用次数: 0

摘要

研究了在K-Bi-V-Mo-O熔盐中合成BiVO4:Mo结晶的条件。该化合物在空间群I2/a单斜晶系中结晶，晶胞参数a = 5.1153(3)， b = 11.7012(1)， c = 5.1878(1) Å， β = 90.24(1)°，Z = 4代表白钨矿相关结构。化合物的分子式为bi0.98 v0.95 mo0.050 o4。

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Synthesis and structure of monoclinic bismuth vanadate doped with molybdenum

The synthetic conditions of BiVO₄:Mo crystallization in the molten salts of K-Bi-V-Mo-O have been studied. The compound crystallizes in the monoclinic system, space group I2/a, with unit cell parameters a = 5.1153(3), b = 11.7012(1), c = 5.1878(1) Å, β = 90.24(1)°, Z = 4 representing scheelite-related structure. The formula of the compound established to be Bi_0.98V_0.95Mo_0.05O₄.

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International Conference on Oxide Materials for Electronic Engineering - fabrication, properties and applications (OMEE-2014)

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