在不均匀加热的流体中作用于极化粒子系统的平均电热电泳力的测定

S. I. Martynov
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引用次数: 0

摘要

在非均匀加热的介质液体中,确定了电场作用于极化粒子体系的平均力。研究了系统中对相互作用的情况。为了找出作用在粒子上的力,在给定温度梯度和远离粒子的电场强度的情况下,模拟了液体中两个粒子的相互作用。考虑了粒子介电常数与温度的关系。作用在两个粒子上的力的结果表达式与粒子之间的距离有幂律关系,这允许对位于无限体积液体中的粒子系统进行直接平均过程。在确定平均力时,采用连续随机变量的概率密度函数,连接质点中心的矢量充当该变量的作用。求概率密度函数的微分方程由两个条件导出。首先,粒子对被保存在它们所有可能构型的空间中。第二,每一对粒子像一个点一样运动,速度等于它们的相对运动速度。在考虑的情况下,得到的方程有一组解。在对问题进行物理分析的基础上,提出了概率密度函数的选择,使人们能够确定作用于这种系统中的平均电热泳力,其精度可达粒子体积浓度的二度。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Determination of the average electro-thermophoretic force acting on a system of polarizable particles in an inhomogeneously heated fluid
The average force acting on the system of polarizing particles from the electric field in a non-uniformly heated dielectric liquid is determined. The case of pair interactions in the system is examined. To find the force acting on the particles, the interaction of two particles in a liquid is modelled in the presence of a given temperature gradient and the electric field strength far from the particles. The dependence of the particle permittivity on temperature is taken into account. The resulting expression for the force acting on two particles has such a power-law dependence on the distance between the particles, that allows to carry out the direct averaging procedure for a system of particles located in an infinite volume of liquid. When determining the average force, the probability density function of a continuous random variable is used, and the vector connecting the centers of particles plays the role of this variable. The differential equation for finding the probability density function is derived from two conditions. First, the pairs of particles are preserved in the space of all their possible configurations. Second, each pair of particles moves like a point with a speed equal to the speed of their relative motion. The resulting equation in the case under consideration has a set of solutions. Basing on the physical analysis of the problem, the choice of the probability density function is proposed, which allows one to determine the average electro-thermophoretic force acting in such a system with an accuracy up to the second degree of the volume concentration of particles.
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