SnO2/Cd0.8Zn0.2S0.1Se0.9/p-CdTe/Cu异质结在可见光和近红外光谱中的光敏性

H. Mamedov, S. I. Amirova
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引用次数: 1

摘要

采用电化学沉积法制备了SnO2/Cd0.8Zn0.2S0.1Se0.9/p-CdTe/Cu薄膜异质结。结果表明,未经处理的异质结仅在可见光区域具有灵敏度。在太阳模拟器W = 100 mVt/sm2照射下,未处理结构的光电参数为:Isc≈4.76 mA/cm2, 0.448 V, D* = 3 × 104 cm × Hz1/2Vt-1。样品在空气中退火后,光敏性显著提高。在t = 350℃,τ = 9 min的温度下,样品在0.8 ~ 1.0 μm波长区域的灵敏度急剧提高,这是由于铜原子从缓冲触点通过CdTe扩散到Cd0.8Zn0.2S0.1Se0.9形成Cu2Se薄膜所致。因此,所研究的结构具有以下短路光电流,开路光电压和可检测性值:1sc = 19.4 mA/cm2, Uoc = 637 mV, D* = 8 × 106 cm × Hz1/2 × Vt-1。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Photosensitivity of SnO2/Cd0.8Zn0.2S0.1Se0.9/p-CdTe/Cu heterojunctions in visible and near IR regions of spectrum
Effective thin film heterojunctions SnO2/Cd0.8Zn0.2S0.1Se0.9/p-CdTe/Cu were manufactured by the method of electrochemical deposition. It is shown, that not treated heterojunctions possess the sensitivity only in visible region of spectrum. At illumination by the solar simulator with W = 100 mVt/sm2, not treated structures had the following photoelectric parameters: Isc ≈ 4.76 mA/cm2, 0.448 V, D* = 3 x 104 cm x Hz1/2Vt-1. Annealing of samples in air results to substantial increase of photosensitivity is found. After TA at t = 350°C and τ = 9 min, the sensitivity of samples in the 0.8 - 1.0 μm wavelength region sharply increase, that is due to formation of films Cu2Se at thermal annealing by means of diffusion of copper atoms from buffer contact through CdTe to Cd0.8Zn0.2S0.1Se0.9. Thus investigated structures possess following values of short circuit photocurrent, open circuit photovoltage and detectability: 1sc = 19,4 mA/cm2, Uoc = 637 mV, D* = 8 x 106 cm x Hz1/2 x Vt-1.
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