聚苯胺/NaFe/sub 4/P/sub 12/复合材料的制备及其热电性能

Proceedings ICT2001. 20 International Conference on Thermoelectrics (Cat. No.01TH8589) Pub Date : 2001-06-08 DOI:10.1109/ICT.2001.979904

Hong Liu, Ji-yang Wang, Xia Hui, Huaidong Jiang, Shanrong Zhao, Qiang Li, R. Boughton, M. Jiang

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引用次数: 0

摘要

采用原位复合法制备了聚苯胺/NaFe/sub 4/P/sub 12/晶须和聚苯胺/NaFe/sub 4/P/sub 12/纳米线复合材料。采用x射线衍射(XRD)、红外光谱、热重分析(TGA)、透射电镜(TEM)和电子衍射(ED)对聚苯胺及其复合材料进行了表征。聚苯胺可以在NaFe/sub 4/P/sub 12/晶须表面生长，形成新颖的“刷”状结构。提出了“刷状”结构形成的机理。测定了聚苯胺及其复合材料的电导率和塞贝克系数。

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Preparation and thermoelectric properties of polyaniline/NaFe/sub 4/P/sub 12/ composite

Polyaniline/NaFe/sub 4/P/sub 12/ whiskers and polyaniline/NaFe/sub 4/P/sub 12/ nanowire composites were prepared by an in situ compounding method. X-ray diffraction (XRD), infrared spectra, thermal gravity analysis (TGA) transmission electron microscope (TEM) and electron diffraction (ED) were used to characterize polyaniline and the composites. Polyaniline can grow on the surface of NaFe/sub 4/P/sub 12/ whisker and forms a novel "brush" structure. The mechanism of the forming of the "brush" structure is suggested. The conductivity and Seebeck coefficient of polyaniline and the composites were measured.

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Proceedings ICT2001. 20 International Conference on Thermoelectrics (Cat. No.01TH8589)

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