含硫油罐内表面形成腐蚀性沉积物的火灾爆炸危险性分析

D. A. Petrilin
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引用次数: 0

摘要

介绍。石油化学工业设施每年发生的火灾数量正在增加。焦性腐蚀性沉积物的自燃是引燃的主要来源之一。含硫油罐火灾造成的巨大损失表明,油罐表面存在形成焦性腐蚀沉积物的严重危险。研究的目的。分析了油罐表面形成热态腐蚀沉积的火灾和爆炸危险性。工作任务:-分析统计发生在石化工业设施的事故;-分析由焦性腐蚀性沉积物自燃引起的火灾;-分析油罐表面形成腐蚀性沉积物的危险,以及针对它们的保护系统。方法。在工作过程中,采用了比较法、描述法、概括法。本研究的资料基础是各种文献资料、规范性文件、油罐场火灾分析资料。结果和讨论。硫磺油储存过程中油罐的操作实践和火灾的起因表明,现代的防腐方法是无效的。在提高石化工业设施防火防爆安全方面,有必要调整现有的法规和法律文件,开发新的、更有效的含硫油储罐防腐保护手段。保护油罐免受腐蚀的方法之一是在油罐的内表面涂上保护涂层。然而,现代防腐涂料不具备所需的防护能力。结论。目前使用的防腐系统不够有效。同时,对含硫油罐内表面防腐涂料的保护问题研究还不够充分。因此,有必要对这一问题进行更深入的研究,以提高含硫油罐的火灾和爆炸安全性。关键词:防火防爆安全,储罐,腐蚀,焦粉,防护,油,硫。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Analysis of the fire and explosion hazard of the formation of corrosive deposits on the inner surface of tanks with sulfurous oil
Introduction. The annual number of fires at the facilities of the petrochemical industry is increasing. Spontaneous combustion of pyrophoric corrosive deposits is one of the main sources of ignition. The large damage caused by fires on tanks with sulfur oil indicates a serious danger of the formation of pyrophoric corrosive deposits on the surface of oil tanks. The purpose of the study. Analyze the fire and explosion hazard of the formation of pyro-form corrosion deposits on the surface of oil tanks. The tasks of the work: - analysis of statistics of accidents that occurred at the facilities of the petrochemical industry; - analysis of fires that occurred due to spontaneous combustion of pyrophoric corrosive deposits; - analysis of the danger of formation of corrosive deposits on the surface of oil tanks, protection systems against them. Methods. In the course of the work, methods of comparison, description, generalization were used. The information basis of the study was various literary sources, regulatory documents, materials of fire analysis at tank farms. Results and discussion. The practice of operating oil tanks during the storage of sulfurous oil and the origin of fires shows that modern methods of corrosion protection are ineffective. It is necessary to adjust the existing regulatory and legal documentation in the field of improving the fire and explosion safety of petrochemical industry facilities, to develop new, more effective means of anticorrosion protection of tanks with sulfurous oil. One of the methods to protect the oil tank from corrosion is to apply protective coatings on the inner surface of the tank. However, modern anticorrosive coatings do not have the required protective ability. Conclusion. The corrosion protection system currently used is insufficiently effective. At the same time, the problem of protecting the inner surface of sulfurous oil tanks by applying anticorrosion paint coatings has not been sufficiently studied. Therefore, a more thorough study of this issue is necessary in order to increase the fire and explosion safety of sulfur oil tanks. Keywords: fire and explosion safety, tank, corrosion, pyrophores, protection, oil, sulfur.
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