氟化锂和氟化镁对LiTaO/sub - 3陶瓷烧结机理的影响

[Proceedings] 1990 IEEE 7th International Symposium on Applications of Ferroelectrics Pub Date : 1990-06-06 DOI:10.1109/ISAF.1990.200315

Z. Ye, R. von der Muhll, J. Ravez

{"title":"氟化锂和氟化镁对LiTaO/sub - 3陶瓷烧结机理的影响","authors":"Z. Ye, R. von der Muhll, J. Ravez","doi":"10.1109/ISAF.1990.200315","DOIUrl":null,"url":null,"abstract":"Highly densified LiNbO/sub 3/ and LiTaO/sub 3/ ceramics were obtained by sintering in a moist atmosphere in the presence of LiF and MgF/sub 2/. The sintering mechanism of LiTaO/sub 3/ ceramics at low temperatures in the presence of LiF and MgF/sub 2/ is reported. The sintering temperatures were decreased by 300 degrees C for LiNbO/sub 3/ and 500 degrees C for LiTaO/sub 3/. An open air sintering mechanism based on the partial hydrolysis of the starting fluorides and the formation of an intermediate Mg/sub 4/M/sub 2/X/sub 9/-type (M=Li,Ta; X=O,F,OH) hydroxofluoride phase is proposed, and a three-stage reactional sketch is given.<<ETX>>","PeriodicalId":269368,"journal":{"name":"[Proceedings] 1990 IEEE 7th International Symposium on Applications of Ferroelectrics","volume":"33 1","pages":"0"},"PeriodicalIF":0.0000,"publicationDate":"1990-06-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"1","resultStr":"{\"title\":\"Sintering mechanism of LiTaO/sub 3/ ceramics by the addition of lithium and magnesium fluorides\",\"authors\":\"Z. Ye, R. von der Muhll, J. Ravez\",\"doi\":\"10.1109/ISAF.1990.200315\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Highly densified LiNbO/sub 3/ and LiTaO/sub 3/ ceramics were obtained by sintering in a moist atmosphere in the presence of LiF and MgF/sub 2/. The sintering mechanism of LiTaO/sub 3/ ceramics at low temperatures in the presence of LiF and MgF/sub 2/ is reported. The sintering temperatures were decreased by 300 degrees C for LiNbO/sub 3/ and 500 degrees C for LiTaO/sub 3/. An open air sintering mechanism based on the partial hydrolysis of the starting fluorides and the formation of an intermediate Mg/sub 4/M/sub 2/X/sub 9/-type (M=Li,Ta; X=O,F,OH) hydroxofluoride phase is proposed, and a three-stage reactional sketch is given.<<ETX>>\",\"PeriodicalId\":269368,\"journal\":{\"name\":\"[Proceedings] 1990 IEEE 7th International Symposium on Applications of Ferroelectrics\",\"volume\":\"33 1\",\"pages\":\"0\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1990-06-06\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"1\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"[Proceedings] 1990 IEEE 7th International Symposium on Applications of Ferroelectrics\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1109/ISAF.1990.200315\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"[Proceedings] 1990 IEEE 7th International Symposium on Applications of Ferroelectrics","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1109/ISAF.1990.200315","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}

引用次数: 1

摘要

在LiF和MgF/sub /存在下，在潮湿气氛下烧结，获得了高密度的LiNbO/sub /和LiTaO/sub /陶瓷。报道了LiTaO/sub - 3/陶瓷在LiF和MgF/sub - 2/存在下的低温烧结机理。LiNbO/ sub3 /的烧结温度降低了300℃，LiTaO/ sub3 /的烧结温度降低了500℃。基于起始氟化物部分水解和中间产物Mg/sub 4/M/sub 2/X/sub 9/型(M=Li,Ta;提出了X=O,F,OH)氢氟化物相，并给出了三段反应简图。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

查看原文本刊更多论文

Sintering mechanism of LiTaO/sub 3/ ceramics by the addition of lithium and magnesium fluorides

Highly densified LiNbO/sub 3/ and LiTaO/sub 3/ ceramics were obtained by sintering in a moist atmosphere in the presence of LiF and MgF/sub 2/. The sintering mechanism of LiTaO/sub 3/ ceramics at low temperatures in the presence of LiF and MgF/sub 2/ is reported. The sintering temperatures were decreased by 300 degrees C for LiNbO/sub 3/ and 500 degrees C for LiTaO/sub 3/. An open air sintering mechanism based on the partial hydrolysis of the starting fluorides and the formation of an intermediate Mg/sub 4/M/sub 2/X/sub 9/-type (M=Li,Ta; X=O,F,OH) hydroxofluoride phase is proposed, and a three-stage reactional sketch is given.<>

求助全文

通过发布文献求助，成功后即可免费获取论文全文。去求助

来源期刊

[Proceedings] 1990 IEEE 7th International Symposium on Applications of Ferroelectrics

自引率

0.00%

发文量