石墨烯双层能否成为膜类材料

O. Gradov
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引用次数: 0

摘要

自从膜模拟化学的创始人Janos H. Fendler的开创性工作以来,人们已经知道许多原子或分子团簇和薄膜(包括纳米级的)能够模仿膜的功能。膜模拟材料可以是软物质也可以是固态材料。导电薄膜(包括具有磁性的薄膜)和半导体也已知具有膜模拟特性。如果我们以操作符的形式考虑介质通过膜的交换,那么膜的化学组成及其模型,以及原子和分子簇或层之间的差异就变得不那么重要了,因此,在基于介质的方法中,纳米和介观结构的膜模拟化学没有显着差异。这篇特邀综述包含几个部分,反映了作者在“石墨烯:分子和2d晶体”会议(2015年9月8-12日,俄罗斯新西伯利亚)上报告的主要方面,并考虑了石墨烯纳米结构、膜和仿生膜样纳米材料之间的相似性。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Can graphene bilayers be the membrane mimetic materials
Since the pioneering works of the founder of membrane mimetic chemistry Janos H. Fendler it is known that a number of atomic or molecular clusters and films (including nanoscale ones) are capable of mimicking the membrane functions. Membrane mimetic materials can be either soft matter or solid state materials. Conducting films (including those with magnetic properties) and semiconductors are also known to possess membrane mimetic properties. If we consider the agent exchange through the membrane in the operator form, the chemical composition of the membranes and their models, as well as the difference between the atomic and molecular clusters or layers become not so essential, and hence, membrane mimetic chemistry of nano- and mesostructures do not differ significantly within the agent-based approach. This invited review containing several parts reflects the main aspects of the author's report at the conference "Graphene: a molecule and 2D-crystal" (September 8-12, 2015, Novosibirsk, Russia) and considers various aspects of the similarity between the graphene nanostructures, membranes and bionic membrane-like nanomaterials.
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