热温和的化学反应(为了避免火灾事故)会产生意想不到的产品吗?

T. Akitsu, Yuika Onami, Natsuki Katsuumi
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引用次数: 2

摘要

化学实验火灾事故最可能和最常见的原因之一可能是在化学反应过程中危险的加热以及试剂本身(例如挥发性和点火)。一些没有加热的反应方法(如在室温下长时间搅拌)和使用先进的工具(如微流体装置),这些反应方法在动力学上与不寻常的中间体有关,可能导致产生意想不到的热力学产物。本文重点介绍了两个复杂的晶体结构分析实例,分析了意外和/但正常产品的晶体结构。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Do Thermally Mild Chemical Reactions (for Avoiding Fire Accidents) Give Rise to Unexpected Products?
One of the most probable and frequent reasons for a chemical experiment fire accident may be dangerous heating as well as the reagent itself (e.g. volatility and ignition) during a chemical reaction. Some reaction methods without heating (such as long-time stirring at room temperature) and using advanced tools (such as a microfluidic device), which are associated with unusual intermediates kinetically and may result in yielding unexpected products thermodynamically. This paper focused on two complicated examples of crystal structure analysis of unexpected and/but normal products.
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