P. Stanić, Darko P Ašanin, M. Vasić, T. Soldatović, Biljana M Šmit
{"title":"芳烯- 2-硫代海因衍生物与某些Pd(II)配合物反应动力学","authors":"P. Stanić, Darko P Ašanin, M. Vasić, T. Soldatović, Biljana M Šmit","doi":"10.46793/sbt28.497s","DOIUrl":null,"url":null,"abstract":"Reactions of 3-(benzylideneamino)-2-thioxoimidazolidin-4-one with some palladium complexes (PdCl2, Pd(DMSO)2Cl2 and K2PdCl4) were monitored with NMR spectroscopy, which is used as a convenient and practical tool for determining the kinetic parameters of the reactions. Rate constants of the reactions were determined and reactivity of the complexes towards the 2-thiohydantoin derivative was compared.","PeriodicalId":106266,"journal":{"name":"1st INTERNATIONAL SYMPOSIUM ON BIOTECHNOLOGY: Proceedings","volume":"97 1","pages":"0"},"PeriodicalIF":0.0000,"publicationDate":"2023-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"KINETICS OF THE REACTION OF AN ARYLIDENE 2-THIOHYDANTOIN DERIVATIVE WITH SOME Pd(II) COMPLEXES\",\"authors\":\"P. Stanić, Darko P Ašanin, M. Vasić, T. Soldatović, Biljana M Šmit\",\"doi\":\"10.46793/sbt28.497s\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Reactions of 3-(benzylideneamino)-2-thioxoimidazolidin-4-one with some palladium complexes (PdCl2, Pd(DMSO)2Cl2 and K2PdCl4) were monitored with NMR spectroscopy, which is used as a convenient and practical tool for determining the kinetic parameters of the reactions. Rate constants of the reactions were determined and reactivity of the complexes towards the 2-thiohydantoin derivative was compared.\",\"PeriodicalId\":106266,\"journal\":{\"name\":\"1st INTERNATIONAL SYMPOSIUM ON BIOTECHNOLOGY: Proceedings\",\"volume\":\"97 1\",\"pages\":\"0\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2023-03-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"1st INTERNATIONAL SYMPOSIUM ON BIOTECHNOLOGY: Proceedings\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.46793/sbt28.497s\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"1st INTERNATIONAL SYMPOSIUM ON BIOTECHNOLOGY: Proceedings","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.46793/sbt28.497s","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
KINETICS OF THE REACTION OF AN ARYLIDENE 2-THIOHYDANTOIN DERIVATIVE WITH SOME Pd(II) COMPLEXES
Reactions of 3-(benzylideneamino)-2-thioxoimidazolidin-4-one with some palladium complexes (PdCl2, Pd(DMSO)2Cl2 and K2PdCl4) were monitored with NMR spectroscopy, which is used as a convenient and practical tool for determining the kinetic parameters of the reactions. Rate constants of the reactions were determined and reactivity of the complexes towards the 2-thiohydantoin derivative was compared.