芳烯- 2-硫代海因衍生物与某些Pd(II)配合物反应动力学

P. Stanić, Darko P Ašanin, M. Vasić, T. Soldatović, Biljana M Šmit
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引用次数: 0

摘要

采用核磁共振波谱法对3-(苄基氨基)-2-硫代咪唑烷-4- 1与钯配合物(PdCl2、Pd(DMSO)2Cl2和K2PdCl4)的反应进行了监测,为测定反应动力学参数提供了方便实用的工具。测定了反应的速率常数,并比较了配合物对2-硫代海因衍生物的反应活性。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
KINETICS OF THE REACTION OF AN ARYLIDENE 2-THIOHYDANTOIN DERIVATIVE WITH SOME Pd(II) COMPLEXES
Reactions of 3-(benzylideneamino)-2-thioxoimidazolidin-4-one with some palladium complexes (PdCl2, Pd(DMSO)2Cl2 and K2PdCl4) were monitored with NMR spectroscopy, which is used as a convenient and practical tool for determining the kinetic parameters of the reactions. Rate constants of the reactions were determined and reactivity of the complexes towards the 2-thiohydantoin derivative was compared.
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