评论:回复“氯的B Π3(0u+)和a Π3(1u)态激光诱导荧光动力学”评论

Laser Chemistry Pub Date : 1900-01-01 DOI:10.1155/1994/48678

E. Martínez, F. Basterrechea, B. Cabañas, P. Puyuelo, M. R. López

{"title":"评论:回复“氯的B Π3(0u+)和a Π3(1u)态激光诱导荧光动力学”评论","authors":"E. Martínez, F. Basterrechea, B. Cabañas, P. Puyuelo, M. R. López","doi":"10.1155/1994/48678","DOIUrl":null,"url":null,"abstract":"The comment of Billy et al.1 on our paper about the dynamics of the B and A states of chlorine2 \nemphasizes mainly two points: a) our results about the radiative decay rate of the B state of Cl2 are \nincorrect, because our experimental system is unable to measure the true long lifetimes of this state; b) \nboth A Π 3 ( 1 u ) and Π 1 ( 1 u ) states contribute to the Coriolis predissociation in the B state, in contradiction \nwith our mechanism, which excludes the Π 1 ( 1 u ) state.","PeriodicalId":296295,"journal":{"name":"Laser Chemistry","volume":"48 1","pages":"0"},"PeriodicalIF":0.0000,"publicationDate":"1900-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Comment: Reply to Comment on “Dynamics of the B Π3(0u+) and a Π3(1u) States of Chlorine by Laser Induced Fluorescence”\",\"authors\":\"E. Martínez, F. Basterrechea, B. Cabañas, P. Puyuelo, M. R. López\",\"doi\":\"10.1155/1994/48678\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"The comment of Billy et al.1 on our paper about the dynamics of the B and A states of chlorine2 \\nemphasizes mainly two points: a) our results about the radiative decay rate of the B state of Cl2 are \\nincorrect, because our experimental system is unable to measure the true long lifetimes of this state; b) \\nboth A Π 3 ( 1 u ) and Π 1 ( 1 u ) states contribute to the Coriolis predissociation in the B state, in contradiction \\nwith our mechanism, which excludes the Π 1 ( 1 u ) state.\",\"PeriodicalId\":296295,\"journal\":{\"name\":\"Laser Chemistry\",\"volume\":\"48 1\",\"pages\":\"0\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1900-01-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Laser Chemistry\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1155/1994/48678\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Laser Chemistry","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1155/1994/48678","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}

引用次数: 0

摘要

Billy等人对我们关于氯气B态和A态动力学的论文的评论主要强调两点:A)我们关于氯气B态的辐射衰减率的结果是不正确的，因为我们的实验系统无法测量出这种状态的真正长寿命;b) A Π 3 (1u)和Π 1 (1u)态都有助于b态的科里奥利预解，这与我们排除Π 1 (1u)态的机制相矛盾。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

查看原文本刊更多论文

Comment: Reply to Comment on “Dynamics of the B Π3(0u+) and a Π3(1u) States of Chlorine by Laser Induced Fluorescence”

The comment of Billy et al.1 on our paper about the dynamics of the B and A states of chlorine2 emphasizes mainly two points: a) our results about the radiative decay rate of the B state of Cl2 are incorrect, because our experimental system is unable to measure the true long lifetimes of this state; b) both A Π 3 ( 1 u ) and Π 1 ( 1 u ) states contribute to the Coriolis predissociation in the B state, in contradiction with our mechanism, which excludes the Π 1 ( 1 u ) state.

求助全文

通过发布文献求助，成功后即可免费获取论文全文。去求助

来源期刊

Laser Chemistry

自引率

0.00%

发文量