臭氧线宽度和强度近1129.4 CM−1

L. N. Majorana, G. Copeland, C. Harward
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引用次数: 0

摘要

随着半导体激光器的出现及其最近在光谱学中的应用(1,2),红外光谱的研究发生了一场革命。使用可调谐二极管激光器(TDL)可以对几种高电流分子(C10,HNO3,SO2,CF2C12等)进行高分辨率(<0.0001 CM−1)的研究。本研究是关于在1129.4 CM−1附近的单个O3线的压力展宽特性的实验测定。这条线已被美国国家航空航天局(NASA)选为使用红外外差光谱或差分激光雷达进行遥感实验的可能候选者,因为它相对较好地隔离于其他大气线,并且具有显著的强度。通过比尔定律实验确定了吸收系数和碰撞自展宽参数。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Ozone Line Widths and Strengths Near 1129.4 CM−1
With the advent of semi-conductor lasers and their recent application to spectroscopy (1,2), there has been a revolution in the study of infrared spectra. Use of the tunable diode laser(TDL) has permitted high resolution (<0.0001 CM−1) studies of several molecules of high current interest (C10,HNO3,SO2,CF2C12,etc.). This study is concerned with the experimental determination of the pressure broadened characteristics of a single O3 line near 1129.4 CM−1. This line has been selected by NASA as a possible candidate for remote sensing experiments using either infrared heterodyne spectroscopy or differential lidar, since it is relatively well isolated from other atmospheric lines and has significant strength. A Beer's Law experiment is performed to determine the absorption coefficients and collisional self-broadening parameters.
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