极性中氮分子三重态合成发射光谱的计算方法

Zh. V. Dashkevich, V. Ivanov
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引用次数: 0

摘要

提出了一种计算分子氮三重态体系合成发射光谱的方法:Vegard- VK N2(A^3 Σ_u^+→X^1 Σ_g^+),第一正极体系1PG N2(〖B〗^3 Π_g→A^3 Σ_u^+),第二正极体系2PG N2(C^3 Π_u→B^3 Π_g)。相应分子的个别结构被考虑在内。考虑碰撞反应中三重态能级之间的能量转移和分子内能量的再分配,计算了三重态振动能级的居群。给出了合成光谱的计算实例。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Method of calculation of synthetic emission spectra of triplet states of molecular nitrogen in apolars
A method for calculating synthetic emission spectra of systems of triplet levels of molecular nitrogen is presented: Vegard- VK N2(A^3 Σ_u^+→X^1 Σ_g^+), the first positive system 1PG N2(〖 B〗^3 Π_g→A^3 Σ_u^+), the second positive system 2PG N2(C^3 Π_u→B^3 Π_g). The individual structures of the corresponding molecules are taken into account. The populations of the vibrational levels of the triplet states are calculated taking into account the energy transfer between triplet levels in collisional reactions and the intramolecular redistribution of energy. Examples of calculation of synthetic spectra are presented.
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