在临界点现象学理论的基础上,利用相似理论求解非参数状态方程

S. Rykov, I. Kudryavtseva, V. Rykov, A. Sverdlov
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引用次数: 1

摘要

除了格里菲斯等式:2 - α = βδ + β和γ = βδ - β外,还认为方程γ = 4β。提出了利用晶格气体模型与实际液体模型的相似关系构造尺度方程的一种变体。这样我们就可以把尺度函数的单个参数减少到一个。以氩气的尺度方程为例,对该方法进行了验证。在临界点统计理论的框架下,用Griffith等式和Bondarev V. n证明的条件γ = 3β来确定临界指标的氩的状态尺度方程进行了比较分析。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Nonparametric equation of state on the basis of the phenomenological theory of a critical point with the use of similarity theory
β and equality γ is considered the equation γ = 4β, in addition to Griffith’s equalities: 2 – α = βδ + β and γ = βδ – β. A variant of constructing a scale equation using the similarity relation between a lattice gas model and a real liquid is proposed. That allowed us to reduce the number of individual parameters of the scale function to one. The proposed approach is tested on the example of constructing the scale equation of argon. A comparative analysis is carried out with the scale equations of state of argon, where the critical indices are specified in accordance with the Griffith equalities and the condition γ = 3β justified by Bondarev V. N. in the framework of the statistical theory of a critical point.
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