气溶胶辅助CVD (AACVD)制备非晶碳及其纳米结构性能

A. N. Fadzilah, K. Dayana, M. Rusop
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引用次数: 1

摘要

以天然樟脑油为前驱体材料,研究了气溶胶辅助气相沉积法(AACVD)制备非晶碳薄膜的可行性。首先将前驱体材料设置在室温和樟脑油蒸发温度(180℃)下,沉积参数确定,而沉积温度设置在500℃恒定。利用太阳模拟器系统、紫外/可见光/近红外光谱仪和FESEM对薄膜的电学、光学和结构性能进行了表征。根据电学性质的表征,模拟了两种条件下的I-V图,并进行了线性图(欧姆),分析表明,当前驱体在蒸发温度下加热时,电导率呈增加趋势,其值为0.1030×10−4 Scm−1到5.8390×10−4 Scm−1(黑暗),从0.1240×10−4 Scm−1到8.1190×10−4 Scm−1(照明)。与电导率相矛盾的是,光学性质表征结果表明,Tauc的带隙为0.7eV和0.3eV,结构性质证明了a-C的纳米结构粒子。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Preparation and nanostructured properties of amorphous carbon prepared by Aerosol-Assisted CVD (AACVD)
The feasibility of Aerosol-Assisted CVD (AACVD) has been investigated for the growth of Amorphous Carbon (a-C) films using natural source of camphor oil as the precursor material. The deposition parameter was first established by setting the precursor material at room temperature and at camphor oil vaporization temperature (180°C), whereas the deposition temperature was set constant at 500°C. Films were characterized by using the Solar Simulator system, UV/VIS/NIR spectrometer and FESEM for electrical, optical and structural properties of the thin films. From the characterization of the electrical properties, I–V graph was modeled for both conditions, and linear graph (ohmic) were performed and the analyze reveal that conductivity shows an increment when the precursor was heated at the vaporization temperature, with the value of 0.1030×10−4 Scm−1 to 5.8390×10−4 Scm−1 (in dark) and from 0.1240×10−4 Scm−1 to 8.1190×10−4 Scm−1 (under illumination). Contradicts from the electrical conductivity, the optical properties characterization results in band gap 0.7eV and 0.3eV from the Tauc's plot and structural properties proves the nanostructured particle of the a-C.
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