{"title":"聚合物薄膜中掺杂染料和染料寡核苷酸的温度退火循环烧孔光谱","authors":"Ta-Chau Chang, C. Chiang, S. Chou","doi":"10.1364/shbs.1994.wd16","DOIUrl":null,"url":null,"abstract":"We have measured the temperature-annealing-cycling hole spectra of 5-(and 6-) carboxy-X-rhodamine N-hydroxy succinimidyl ester (RhSE) and the RhSE molecule with binding to the oligonucleotide of ten bases of Guanine (RhSE-10G) doped in polyvinyl alcohol (PVOH) films, respectively. Figure 1 shows the temperature-annealing-cycling hole spectra of zero phonon hole (ZPH) of RhSE/PVOH and RhSE-10G/PVOH, which were taken after burning 5 and 10 mins with a flux of ~ 40 mW/cm2 at λB ~ 5812 Å, respectively. It is found that the holes are reduced by 40 % and 50 % in the annealing spectra at Ta ~ 18 K. However, part of the holes are recovered when the systems are cycled back to the burning temperature at Tc = 6 K. It is found that the hole reduction in the annealing spectrum of RhSE-10G/PVOH is more dominant than that of RhSE/PVOH.","PeriodicalId":443330,"journal":{"name":"Spectral Hole-Burning and Related Spectroscopies: Science and Applications","volume":"93 1","pages":"0"},"PeriodicalIF":0.0000,"publicationDate":"1900-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Temperature-Annealing-Cycling Hole Burning Spectroscopies of Dye and Dye-Oligonucleotide Doped in Polymer Films\",\"authors\":\"Ta-Chau Chang, C. Chiang, S. Chou\",\"doi\":\"10.1364/shbs.1994.wd16\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"We have measured the temperature-annealing-cycling hole spectra of 5-(and 6-) carboxy-X-rhodamine N-hydroxy succinimidyl ester (RhSE) and the RhSE molecule with binding to the oligonucleotide of ten bases of Guanine (RhSE-10G) doped in polyvinyl alcohol (PVOH) films, respectively. Figure 1 shows the temperature-annealing-cycling hole spectra of zero phonon hole (ZPH) of RhSE/PVOH and RhSE-10G/PVOH, which were taken after burning 5 and 10 mins with a flux of ~ 40 mW/cm2 at λB ~ 5812 Å, respectively. It is found that the holes are reduced by 40 % and 50 % in the annealing spectra at Ta ~ 18 K. However, part of the holes are recovered when the systems are cycled back to the burning temperature at Tc = 6 K. It is found that the hole reduction in the annealing spectrum of RhSE-10G/PVOH is more dominant than that of RhSE/PVOH.\",\"PeriodicalId\":443330,\"journal\":{\"name\":\"Spectral Hole-Burning and Related Spectroscopies: Science and Applications\",\"volume\":\"93 1\",\"pages\":\"0\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1900-01-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Spectral Hole-Burning and Related Spectroscopies: Science and Applications\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1364/shbs.1994.wd16\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Spectral Hole-Burning and Related Spectroscopies: Science and Applications","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1364/shbs.1994.wd16","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Temperature-Annealing-Cycling Hole Burning Spectroscopies of Dye and Dye-Oligonucleotide Doped in Polymer Films
We have measured the temperature-annealing-cycling hole spectra of 5-(and 6-) carboxy-X-rhodamine N-hydroxy succinimidyl ester (RhSE) and the RhSE molecule with binding to the oligonucleotide of ten bases of Guanine (RhSE-10G) doped in polyvinyl alcohol (PVOH) films, respectively. Figure 1 shows the temperature-annealing-cycling hole spectra of zero phonon hole (ZPH) of RhSE/PVOH and RhSE-10G/PVOH, which were taken after burning 5 and 10 mins with a flux of ~ 40 mW/cm2 at λB ~ 5812 Å, respectively. It is found that the holes are reduced by 40 % and 50 % in the annealing spectra at Ta ~ 18 K. However, part of the holes are recovered when the systems are cycled back to the burning temperature at Tc = 6 K. It is found that the hole reduction in the annealing spectrum of RhSE-10G/PVOH is more dominant than that of RhSE/PVOH.