取代对Na3Sc2(1-x)M2x(PO4)3 (M = Cr, Yb)固溶体离子电导率和相变的影响

2020 7th International Congress on Energy Fluxes and Radiation Effects (EFRE) Pub Date : 2020-09-14 DOI:10.1109/EFRE47760.2020.9242182

A. Nogai, A. Nogai, S. Stefanovich, Jusupbek Salikhodzha, D. Uskenbayev

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引用次数: 0

摘要

本文研究了Na3SC2(1-x)M2x(PO4)3固溶体在M = Cr, Yb浓度范围x = 0 ～ 0.03时的相变和导电性能。阐明了所研究的固溶体中$\alpha$ -相和$\beta$ -相、$\gamma$ -相离子电导率的特性。建立了M = Sc, Cr时取代Na3SC2(1-x)M2x(PO4)3固溶体相变温度$T_{\alpha\rightarrow\beta}$和$T_{\beta\rightarrow\gamma}$的浓度依赖性。

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Substitutions Influence on Ionic Conductivity and Phase Transitions of Solid Solutions Na3Sc2(1-x)M2x(PO4)3, where M = Cr, Yb

This article researched the phase transitions and conductive properties of solid solutions Na₃SC_2(1-x)M_2x(PO₄)₃, where M = Cr, Yb in the concentration range x = 0 - 0.03. The peculiarities of ionic conductivity in the $\alpha$- and $\beta$-, $\gamma$- phases of the studied solid solutions were clarified. The concentration dependences of the phase transition temperatures $T_{\alpha\rightarrow\beta}$ and $T_{\beta\rightarrow\gamma}$ of solid solutions of substitution Na₃SC_2(1-x)M_2x(PO₄)₃, where M = Sc, Cr have been established.

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2020 7th International Congress on Energy Fluxes and Radiation Effects (EFRE)

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