厚度对有机太阳能电池用MEH-PPV:TiO2纳米复合材料电学和光学性能的影响

F. Zahid, M. Sarah, M. Rusop
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引用次数: 2

摘要

研究了不同厚度的有机/无机纳米复合聚[2-甲氧基5-(2′-乙基己氧基)-1,4-苯基乙烯](MEH-PPV):TiO2薄膜的性能和性能。在室温下,采用旋涂法在氧化铟锡(ITO)衬底上制备了MEH-PPV:TiO2纳米复合薄膜,沉积时间为1 ~ 10次。在AM 1.5、100mW/cm2白光照射和紫外-可见-近红外分光光度计下,利用太阳模拟器研究了不同厚度对MEH-PPV:TiO2电学和光学性能的影响。从电流-电压(I-V)测量结果可以看出,经过3次沉积,在719.413 nm的厚度处光导率最高,为35.2336×103 S.m−1。而对于5倍、7倍和10倍的沉积,光电导率没有明显改善。光学性质与纳米复合薄膜的厚度密切相关。吸收系数随厚度的增加而增加,在可见光波段500 nm和紫外波段310 nm处吸收较强。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Effect of thickness on the electrical and optical properties of MEH-PPV:TiO2 nanocomposite for organic solar cell application
The performance and properties of organic/inorganic nanocomposited poly[2-methoxy 5-(2′-ethyl-hexyloxy)-1,4-phenylene vinylene] (MEH-PPV):TiO2 thin film at different thickness was investigated. MEH-PPV:TiO2 nanocomposite thin film has been prepared on indium tin oxide (ITO) substrate using spin-coating method with different deposition time from 1 to 10 times at room temperature. The effect of different thickness on the electrical and optical properties of MEH-PPV:TiO2 was characterized by using solar simulator under AM 1.5, 100mW/cm2 white light illumination and UV-Vis-NIR spectrophotometer respectively. From the current-voltage (I–V) measurement the result shows for 3 times of deposition, at thickness 719.413 nm gives the highest photoconductivity value, 35.2336×103 S.m−1. While for photoconductivity of 5, 7 and 10 times of deposition, there is no significant improvement were obtained. The optical properties were found to be strongly dependent on the thickness of nanocomposite thin films. The absorption coefficient reveals an improvement as the number of thickness increases with strong absorption at wavelength of 500 nm in visible ranges and 310 nm in UV ranges respectively.
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