{"title":"氧化锰八面体分子筛(OMS-2)在有机化合物清洁合成中的应用","authors":"赵 培庆, 毕 秀茹","doi":"10.3724/SP.J.7103291367","DOIUrl":null,"url":null,"abstract":": The manganese oxide octahedral molecular sieve ( O M S -2) , because of its excellent oxidation , adsorp tion , ion - exchange , and conductivity properties , was wildly used in various fields such as environmental , semicon ductor , synthetic organic . Because of the mixed valency in the framework and abundant surface defect vacancy , O M S -2 could effectively activate green oxidants such as oxygen and hydrogen peroxide , making it an effective heter ogeneous catalyst and functional supporterin clean synthesis of organic molecules . Moreover , the O M S -2 catalysis material exhiliited excellent activity , selectivity , and structural stability . W e reviewed O M S -2 as heterogeneous cat alyst and electron transfer medium (also as functional supporter in supported catalysts ) in the clean oxidation syn thesis of organic molecules . Finally , the existing problems and future development of O M S -2 -catalyzed oxidations were","PeriodicalId":412338,"journal":{"name":"Journal of Molecular Catalysis(China)","volume":"4 1","pages":"0"},"PeriodicalIF":0.0000,"publicationDate":"2020-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Application of Manganese Oxide Octahedral Molecular Sieves(OMS-2)in Clean Synthesis of Organic Compounds\",\"authors\":\"赵 培庆, 毕 秀茹\",\"doi\":\"10.3724/SP.J.7103291367\",\"DOIUrl\":null,\"url\":null,\"abstract\":\": The manganese oxide octahedral molecular sieve ( O M S -2) , because of its excellent oxidation , adsorp tion , ion - exchange , and conductivity properties , was wildly used in various fields such as environmental , semicon ductor , synthetic organic . Because of the mixed valency in the framework and abundant surface defect vacancy , O M S -2 could effectively activate green oxidants such as oxygen and hydrogen peroxide , making it an effective heter ogeneous catalyst and functional supporterin clean synthesis of organic molecules . Moreover , the O M S -2 catalysis material exhiliited excellent activity , selectivity , and structural stability . W e reviewed O M S -2 as heterogeneous cat alyst and electron transfer medium (also as functional supporter in supported catalysts ) in the clean oxidation syn thesis of organic molecules . Finally , the existing problems and future development of O M S -2 -catalyzed oxidations were\",\"PeriodicalId\":412338,\"journal\":{\"name\":\"Journal of Molecular Catalysis(China)\",\"volume\":\"4 1\",\"pages\":\"0\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2020-10-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Molecular Catalysis(China)\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.3724/SP.J.7103291367\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Molecular Catalysis(China)","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.3724/SP.J.7103291367","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 0
摘要
氧化锰八面体分子筛(O M S -2)由于其优异的氧化、吸附、离子交换和导电性能,在环境、半导体、有机合成等领域得到了广泛的应用。由于O M S -2骨架内的混合价态和丰富的表面缺陷空位,可以有效激活氧和过氧化氢等绿色氧化剂,成为清洁合成有机分子的有效异相催化剂和功能载体。此外,O M S -2催化材料表现出优异的活性、选择性和结构稳定性。本文综述了oms2作为非均相催化剂和电子传递介质(也可作为负载型催化剂的功能载体)在有机分子清洁氧化合成中的应用。最后,对O - M - S -2催化氧化存在的问题及今后的发展方向进行了展望
Application of Manganese Oxide Octahedral Molecular Sieves(OMS-2)in Clean Synthesis of Organic Compounds
: The manganese oxide octahedral molecular sieve ( O M S -2) , because of its excellent oxidation , adsorp tion , ion - exchange , and conductivity properties , was wildly used in various fields such as environmental , semicon ductor , synthetic organic . Because of the mixed valency in the framework and abundant surface defect vacancy , O M S -2 could effectively activate green oxidants such as oxygen and hydrogen peroxide , making it an effective heter ogeneous catalyst and functional supporterin clean synthesis of organic molecules . Moreover , the O M S -2 catalysis material exhiliited excellent activity , selectivity , and structural stability . W e reviewed O M S -2 as heterogeneous cat alyst and electron transfer medium (also as functional supporter in supported catalysts ) in the clean oxidation syn thesis of organic molecules . Finally , the existing problems and future development of O M S -2 -catalyzed oxidations were