氧化锰八面体分子筛(OMS-2)在有机化合物清洁合成中的应用

赵 培庆, 毕 秀茹
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摘要

氧化锰八面体分子筛(O M S -2)由于其优异的氧化、吸附、离子交换和导电性能,在环境、半导体、有机合成等领域得到了广泛的应用。由于O M S -2骨架内的混合价态和丰富的表面缺陷空位,可以有效激活氧和过氧化氢等绿色氧化剂,成为清洁合成有机分子的有效异相催化剂和功能载体。此外,O M S -2催化材料表现出优异的活性、选择性和结构稳定性。本文综述了oms2作为非均相催化剂和电子传递介质(也可作为负载型催化剂的功能载体)在有机分子清洁氧化合成中的应用。最后,对O - M - S -2催化氧化存在的问题及今后的发展方向进行了展望
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Application of Manganese Oxide Octahedral Molecular Sieves(OMS-2)in Clean Synthesis of Organic Compounds
: The manganese oxide octahedral molecular sieve ( O M S -2) , because of its excellent oxidation , adsorp tion , ion - exchange , and conductivity properties , was wildly used in various fields such as environmental , semicon ­ ductor , synthetic organic . Because of the mixed valency in the framework and abundant surface defect vacancy , O M S -2 could effectively activate green oxidants such as oxygen and hydrogen peroxide , making it an effective heter ­ ogeneous catalyst and functional supporterin clean synthesis of organic molecules . Moreover , the O M S -2 catalysis material exhiliited excellent activity , selectivity , and structural stability . W e reviewed O M S -2 as heterogeneous cat ­ alyst and electron transfer medium (also as functional supporter in supported catalysts ) in the clean oxidation syn ­ thesis of organic molecules . Finally , the existing problems and future development of O M S -2 -catalyzed oxidations were
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