硅基疏水膜在生物柴油净化过程中的性能研究

R. Oktavian, B. Poerwadi, S. Supriyono, C. W. Kartikowati, Hardo Triwahyu Septiadi, Muhammad Ichya` Yuniardi
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引用次数: 1

摘要

甘油会对柴油发动机造成燃油滤清器堵塞、喷油器结垢、储罐底部形成沉积物等负面影响,必须按照SNI要求进行净化,以提高生物柴油的质量。到目前为止,分离过程是使用聚丙烯疏水聚合物膜进行的。因此,需要另一种膜替代品来提炼生物柴油生产过程,这些生物柴油取材于容易获得且具有经济价值的材料。在本研究中,对FAME与甘油分离过程中疏水二氧化硅复合膜的合成过程及该膜的性能进行了研究。本研究考察了疏水二氧化硅复合膜在生物柴油净化中的性能,以提高酯交换过程产生的生物柴油的质量。结果表明,本研究的膜合成可制得接触角大于90°(150°)的疏水膜。该疏水膜可用于cpo -水的分离,截留系数为0.99。此外,从流量为3 ml / min的试验结果来看,从其热值参数来看,该膜能够提高粗生物柴油的质量。膜通量为8.1 L / m2.h。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Performance Study of Silica-based Hydrofobic membranes in Biodiesel Purification Process
Glycerol can cause negative effects on diesel engines such as fuel filter blockage, fouling on fuel injectors and deposit formation at the bottom of the storage tank, it is necessary to do purification to improve the quality of biodiesel in accordance with SNI. Until now, the separation process has been carried out by using a polypropylene hydrophobic polymer membrane. Therefore, another membrane alternative is needed for the refining process of biodiesel production derived from materials that are easy to obtain and of economic value. In this research, the synthesis process of hydrophobic silica composite membrane and the performance of this membrane were carried out in the process of separating FAME with glycerol. This study examines the performance of the hydrophobic silica composite membrane on biodiesel purification for improving the quality of biodiesel resulting from the transesterification process. The results showed that membrane synthesis in this study could produce a hydrophobic membrane with a contact angle above 90 ° (150 °). This hydrophobic membrane can be used in the process of separating CPO-water with a rejection coefficient of 0.99. In addition, from the test results with a flow rate of 3 ml / minute, it was found that this membrane was able to improve the quality of crude biodiesel seen from the parameters of its heating value. In addition, membrane fluxes were 8.1 L / m2.h.
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