{"title":"固体和液体离子交换剂的性质。2庚烷中二烷基萘磺酸锂盐和铯盐的红外和核磁共振研究。","authors":"V Soldatov, L Odberg, E Högfeldt","doi":"","DOIUrl":null,"url":null,"abstract":"<p><p>Infrared and NMR measurements on solutions of lithium and cesium dinonylnaphtalene sulfonates (DNNS-salts) in heptane show that the state of water in these systems is in several respects similar to its state in solid ion exchange resins and in some respects also similar to that in ordinary water. The two cations differ in their interaction with the sulfonic acid group at low water contents, the interaction being stronger for Li+. Spin-lattice relaxation measurements on LiDNNS show that the state of lithium both in DNNS and in solid resins is quite different from that of lithium salts in aqueous solutions of the corresponding concentration.</p>","PeriodicalId":77184,"journal":{"name":"Ion exchange and membranes","volume":"2 2","pages":"83-90"},"PeriodicalIF":0.0000,"publicationDate":"1975-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"On the properties of solid and liquid ion exchangers. II. Infrared and NMR studies of lithium and cesium salts of dinonylnaphtalene sulfonic acid in heptane.\",\"authors\":\"V Soldatov, L Odberg, E Högfeldt\",\"doi\":\"\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p><p>Infrared and NMR measurements on solutions of lithium and cesium dinonylnaphtalene sulfonates (DNNS-salts) in heptane show that the state of water in these systems is in several respects similar to its state in solid ion exchange resins and in some respects also similar to that in ordinary water. The two cations differ in their interaction with the sulfonic acid group at low water contents, the interaction being stronger for Li+. Spin-lattice relaxation measurements on LiDNNS show that the state of lithium both in DNNS and in solid resins is quite different from that of lithium salts in aqueous solutions of the corresponding concentration.</p>\",\"PeriodicalId\":77184,\"journal\":{\"name\":\"Ion exchange and membranes\",\"volume\":\"2 2\",\"pages\":\"83-90\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1975-12-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Ion exchange and membranes\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Ion exchange and membranes","FirstCategoryId":"1085","ListUrlMain":"","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
On the properties of solid and liquid ion exchangers. II. Infrared and NMR studies of lithium and cesium salts of dinonylnaphtalene sulfonic acid in heptane.
Infrared and NMR measurements on solutions of lithium and cesium dinonylnaphtalene sulfonates (DNNS-salts) in heptane show that the state of water in these systems is in several respects similar to its state in solid ion exchange resins and in some respects also similar to that in ordinary water. The two cations differ in their interaction with the sulfonic acid group at low water contents, the interaction being stronger for Li+. Spin-lattice relaxation measurements on LiDNNS show that the state of lithium both in DNNS and in solid resins is quite different from that of lithium salts in aqueous solutions of the corresponding concentration.
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