碳纳米管的合成与纯化

S. A. Rouf, Z. Usman, Hafiz Tariq Masood, A. Majeed, M. Sarwar, W. Abbas
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引用次数: 0

摘要

在本章中,我们将对碳纳米管的合成和纯化进行综述。碳纳米管是由石墨烯(由单层碳原子卷起)组成的圆柱形分子。电弧放电合成、激光烧蚀石墨/激光汽化合成、化学气相沉积(CVD)、高压一氧化碳合成和火焰合成技术等多种合成技术已被应用于单壁和多壁碳纳米管的生长。上述所有方法都利用过渡金属,如铁、钴和镍作为催化剂。有许多方法(过滤、色谱和离心)用于纯化碳纳米管,但这些方法的纯度仍然存在问题。为了提高净化程度,介绍了气相净化、液相净化和插层净化等替代技术。下面我们就来讨论一下这些净化路线的优缺点。这将有助于研究人员选择合适、有效的碳纳米管合成和纯化方法。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Synthesis and Purification of Carbon Nanotubes
In this chapter, we will evaluate the synthesis and purification of carbon nanotubes. Carbon nanotubes are cylindrical molecules that consists of graphene (rolled up of a single-layer carbon atom). A wide variety of synthesis techniques such as arc discharge synthesis, laser ablation of graphite/laser vaporization synthesis method, chemical vapor deposition (CVD), high pressure carbon monoxide synthesis and flame synthesis techniques, have been implemented to grow single and multi-walled carbon nanotubes for technological applications. All of the above methods exploit transition metals, like iron, cobalt, and nickel, as a catalyst. There are number of methods (filtering, chromatography and centrifugation) used to purify the carbon nanotubes, but the degree of purity remained questionable in these methods. In order to enhance the purification extent, alternate techniques such as Gas phase purification, Liquid phase purification and Purification by Intercalation are introduced. Here we will discuss the advantages and disadvantages of these purification routes. It will help researchers in selecting appropriate and effective method for synthesis and purification of carbon nanotubes.
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