杏干燥过程中β-胡萝卜素含量的目视和近红外光谱评价

Martin Dejanov
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引用次数: 0

摘要

无损检测食品质量,特别是内部性质的应用与食品工业的过程控制高度相关。在这方面,评估和比较了可见光和近红外光谱(VIS和NIR)预测杏中β-胡萝卜素含量的能力。分析了400-1000 nm区域的VIS-NIR和900-1700 nm区域的NIR预测能力。本文采用了两种表征β-胡萝卜素含量的回归模型:偏最小二乘回归(PLSR)和支持向量机回归(SVMR),在两个光谱范围内均得到了较好的确定系数(R2)和交叉验证标准误差(RMSECV)。在VIS-NIR范围内,采用PLS和SVM回归的SNV->SG预处理获得了最佳的模型校准和验证性能。性能测量如下:R2c=0.91, RMSEC=20.1用于校准;R2v=0.84, RMSEV=27.1用于验证。另一方面,支持向量机回归(SVMR)的结果如下:R2c=0.92, RMSEC=19.2用于校准,R2v=0.84, RMSEV=26.7用于验证。当使用二阶导数Savitzky-Golay (SG”)时,两种模型都表现出较差的性能。在此基础上,建立了杏干燥过程中β-胡萝卜素含量的多项式线性回归方程。结果表明,采用不同的预测模型,近红外光谱和近红外光谱均可用于杏中β-胡萝卜素含量的无损测定。本研究在可见光-近红外光谱范围内获得了最佳模型。结论是,有一个工作要做,以提高预测。干燥过程模型的方差仍然较大。虽然参考值与预测值接近,但浓度的估计误差仍不能令人满意。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Evaluation of β-carotene content in apricots during the drying process using visual and near-infrared spectroscopy
Non-destructive applications for the detection of food quality, especially internal properties, are highly relevant for process control in the food industry. In this respect, visible and near-infrared spectroscopy (VIS and NIR) were evaluated and compared for their ability to predict β-carotene content in apricots. Two regions called VIS-NIR from 400–1000 nm and called NIR from 900–1700 nm regions were analyzed for prediction ability. In the paper two types of regression models that present the β-carotene content are used: partial least square regression (PLSR) and support vector machine regression (SVMR) developed in both spectrum ranges, with good results for coefficient of determination (R2) and standard errors of cross-validation (RMSECV). The best model performance for calibration and validation is obtained using SNV->SG pre-treatment with PLS and SVM regressions in the VIS-NIR range. The performance measurements are as follows: R2c=0.91 and RMSEC=20.1 for calibration and R2v=0.84 and RMSEV=27.1 for validation. On the other hand Support Vector Machine Regression (SVMR) has the following results: R2c=0.92 and RMSEC=19.2 for calibration and R2v=0.84 and RMSEV=26.7 for validation. When using second derivative Savitzky-Golay (SG’’) both models showed a poor performance. On the basis of the developed models the polynomial linear regression and equations are developed to evaluate the β-carotene content during the apricots drying process. The results show that the both ranges VIS-NIR and NIR can be used for non-destructive and reliable determination of β-carotene content in apricots using different kinds of predictive models. In this study the best model is obtained in the VIS-NIR range. The conclusion is that there is a work to be done for improving the prediction. The variance of the drying process model is still large. Despite the closeness between the reference values and the predicted ones, the error in estimating the concentration is still not satisfactory.
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