托尔盖盆地南部aryskum凹陷油气潜力探讨

R. Madisheva, V. S. Portnov
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摘要

本文讨论了为比较中生代和前中生代地层油的组成而进行的实验室研究:用色谱-质谱法综合分析油的分子组成;气液色谱法分离鉴定烷烃的组成核磁共振光谱法测定油的碎片组成质谱法测定了碳的同位素组成,从而确定了与油气形成区有关的碳氢化合物的成因。研究结果为揭示地堑-向斜不同年代沉积的油的相似性提供了实验数据,即:地球化学参数的接近值和各类生物标记物的相对含量使得我们可以假设阿克沙布拉克地堑向斜下白垩统和元古界的原油和阿克赛地垒背斜下白垩统和古生界的原油的成因是一致的。原石/植烷比值值表明,两套构造具有共同的初始有机质形成环境——阿克沙布拉克地堑向斜的亚氧化条件和阿克赛地垒背斜的氧化条件,博辛根地堑向斜具有较高的氧化还原电位。气液色谱数据显示,所研究的油的热转化略有差异,被归类为“成熟”。结合其他方法的核磁共振光谱分析结果表明,阿克沙布拉克地堑-向斜下白垩统和元古界的原油和阿克赛地堑-向斜下白垩统和古生界的原油具有统一的成因。通过对Aryskum坳陷侏罗系和白垩系原油与世界各盆地原油碳同位素组成的对比分析,发现其碳同位素组成的变化范围相似,并认为这些原油可能与泥岩型有机质有一定的成因关系。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
ABOUT OIL AND GAS POTENTIAL OF THE ARYSKUM DEPRESSION OF THE SOUTH TORGAI SEDIMENTARY BASIN
The article discusses laboratory studies carried out to compare the composition of oils from Mesozoic and pre-Mesozoic formations: a comprehensive analysis of the molecular composition of oils by chromatography-mass spectrometry; separation and identification of the composition of alkanes by gas-liquid chromatography; NMR-spectroscopic determination of the fragment composition of oils; mass spectrometry was used to determine the isotopic composition of carbon, which identifies the genesis of hydrocarbons in relation to the zones of oil and gas formation. As a result of the study, the laboratory data were obtained, which made it possible to reveal the similarity between oils from deposits of different ages within the graben-synclines, namely, close values of geochemical parameters and the relative content of individual classes of biomarkers made it possible to assume the genetic unity of oils from the Lower Cretaceous and Proterozoic of the Akshabulak graben-syncline and genetic unity of oils from the Lower Cretaceous and Paleozoic of the Aksai horst anticline. The value of the pristane/ phytane ratios indicates a common environment for the formation of the initial organic matter within the structures - suboxidizing conditions in the Akshabulak graben syncline and oxidizing conditions in the Aksai horst anticline, and the existence of a higher redox potential in the Bosingen graben-syncline. Gas- liquid chromatography data showed a slight difference in the thermal transformation of the studied oils, which were classified as "mature". The results of NMR spectrometry in combination with other methods indicate the genetic unity of oils from the Lower Cretaceous and Proterozoic of the Akshabulak graben- syncline and the genetic unity of oils from the Lower Cretaceous and Paleozoic of the Aksai horst anticline. A comparative analysis of the carbon isotopic composition of oils from the Jurassic and Cretaceous deposits of the Aryskum depression and oils from various basins of the world showed a similar range of their variations and a possible genetic relationship of these oils with organic matter of the sapropel type.
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