气相色谱中的线形。3制备柱中的溶质-溶质相互作用

D. Wilson
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引用次数: 4

摘要

摘要采用描述溶质运动的耦合微分方程组的数值积分方法模拟了溶质-溶质相互作用对制备气相色谱谱带形状的影响。这大大减少了理论平板法固有的数值色散。用微型计算机进行计算。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Line Shapes in Gas Chromatography. III. Solute-Solute Interactions in Preparative Columns
Abstract The effects of solute-solute interactions on the shapes of the bands in preparative gas chromatography are modeled by numerical integration of the coupled sets of differential equations describing solute movement An asymmetrical upwind algorithm is used to describe advection; this greatly reduces the numerical dispersion which is inherent in the theoretical plate method. A microcomputer was used for doing the computations.
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