The simulation of vibrational populations of electronically excited N2and O2molecules in the middle atmosphere of the Earth during precipitations of high-energetic particles.

We study the electronic kinetics of molecular nitrogen and molecular oxygen in the middle atmosphere of the Earth during precipitations of high-energetic protons and electrons.The role of molecular inelastic collisions in intermolecularelectron energy transfer processes is investigated.It is shown that inelastic molecular collisions influence on vibrational populations of electronically excited molecular oxygen. It is pointed out on very important role of the collisions of N2(A3u+) with O2molecules on the electronic excitation of Herzberg states of molecular oxygenat the altitudes of the middle atmosphere.