a-Si/介孔ZnO串联太阳能电池的光电性能

Guizhi Wu, Yue Shen, Wanxi Cheng, Feng Gu, Jian-cheng Zhang
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引用次数: 0

摘要

采用水热法合成了用于a-Si/介孔串联太阳能电池的介孔ZnO纳米晶。采用x射线衍射(XRD)、透射电子显微镜(TEM)和基于氮吸附等温线的brunauer - emmet - teller (BET)分析对其结构和形貌进行了表征。测试结果表明,样品的平均孔径为17 nm, BET比表面积约为37.5 m2/g。采用化学处理方法在氟-锡-氧化物(FTO)镀膜玻璃表面制备了透明的a-Si薄膜,并将其用于制备a-Si/介孔ZnO串联太阳能电池。在AM 1.5照射下,a- Si/介孔串联太阳能电池的开路电压(Voc)为560 mV,短路电流(Jsc)为3.61 mA/cm2,转换效率为0.28%。串联太阳能电池的转换效率明显高于透明的a-Si薄膜,而透明的a-Si薄膜在化学处理过程中失去了太阳能电池的特殊性能。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Photoelectric properties of a-Si/mesoporous ZnO tandem solar cells
Mesoporous nanocrystalline ZnO applied to a-Si/mesoporous tandem solar cell was synthesized through the hydrothermal method. The structures and morphologies were characterized by X-ray Diffraction (XRD), Transmission Electron Microscopy (TEM) and Brunauer-Emmett-Teller (BET) analysis based on the nitrogen adsorption isotherm. The test results indicated that the samples had an average pore size of 17 nm and the BET specific surface area was approximately 37.5 m2/g. The transparent a-Si film on fluorine-tin-oxide (FTO) coated glass was obtained by chemical treatment and was used to structure a-Si/mesoporous ZnO tandem solar cell. Under AM 1.5 irradiation, the a- Si/mesoporous tandem solar cell had an open circuit voltage (Voc) of 560 mV, a short circuit current (Jsc) of 3.61 mA/cm2 and a conversion efficiency of 0.28%. The conversion efficiency of tandem solar cell was improved obviously than that of the transparent a-Si film, which had lost special solar cell properties in chemical processing.
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