墙体建筑材料的等离子体化学改性

Vasiliy Bessmertnyy, O. Puchka, D. Bondarenko, I. A. Antropova, L. Bragina
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引用次数: 4

摘要

本研究的目的是研究高温等离子体炬对石英砂和中空玻璃微球混合物作为填料的混凝土保护和装饰涂层相变和逐层改性过程的影响。主要工作包括:研究等离子体涂层氧化物的蒸发和热扩散过程;熔接保护装饰涂层快速自冷过程中熔体相变及其后续结晶的研究钠液玻璃对氧化铝多晶转变过程及氧化钠强扩散形成微芯的影响研究防护和装饰涂料的工作特性研究。结果表明,保护装饰涂层的初始相为α-Al2O3和CaO∙6Al2O3 (β-Al2O3),涂层中的液态玻璃钠还导致了Na2O∙11Al2O3的形成。保护和装饰涂层的顶层是Na-Ca-Al-Si玻璃,其非均质区域含有增加的氧化钠含量。高铝耐火材料防护装饰涂料中氧化铝含量为95.1%。将钠液玻璃引入涂层组合物中,最大限度地减少了结合组分的脱水过程,并改变了防护和装饰涂层的化学组成。氧化铝含量降低到83.0%,影响显微硬度指标。由于液体玻璃的引入,混凝土表面的显微硬度从2510 HV降低到887 HV。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
PLASMOCHEMICAL MODIFICATION OF WALL BUILDING MATERIALS
the aim of the work is to study the effect of a high-temperature plasma torch on the processes of phase transformations and layer-by-layer modification of the protective and decorative coating on concrete using as a filler a mixture of quartz sand and hollow glass microspheres. The main tasks included: investigation of the processes of evaporation and thermal diffusion of oxides of plasma-coated coatings; study of phase transformations in the melt and its subsequent crystallization in the process of rapid spontaneous cooling of the fused protective and decorative coating; study of the effect of sodium liquid glass on the processes of polymorphic transformations of alumina and the formation of micro-wicks due to the intense diffusion of sodium oxide; study of operational characteristics of protective and decorative coatings. It was established that the initial phases in the protective-decorative coating are α-Al2O3 and CaO∙6Al2O3 (β-Al2O3), and the liquid sodium glass in the coating leads additionally to the formation of Na2O∙11Al2O3. The top layer of the protective and decorative coating is Na–Ca–Al–Si glass with regions of heterogeneities containing an increased content of sodium oxide. The content of aluminum oxide in the protective and decorative coating based on the battle of high-alumina refractory was 95.1 %. The introduction into the coating composition of sodium liquid glass minimizes the processes of dehydration of the binding component and changes the chemical composition of the protective and decorative coating. Reduction of the aluminum oxide content to 83.0 % affects the microhardness indicators. Microhardness of the concrete surface due to the introduction of liquid glass is reduced from 2510 HV to 887 HV.
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