MIxNa4−xCoFe(PO4)3 (MI - Li, K)成分玻璃陶瓷样品的合成、表征及电学性能

International Conference on Oxide Materials for Electronic Engineering - fabrication, properties and applications (OMEE-2014) Pub Date : 2014-05-26 DOI:10.1109/OMEE.2014.6912365

M. Bondarenko, N. Strutynska, I. Zatovsky, R. Kuzmin, N. Slobodyanik

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引用次数: 0

摘要

采用熔融法制备了MIxNa4-xCoFe(PO4)3 (x = 0,0.2和1.0,MI - Li, K)组成的玻璃样品。在600℃的退火条件下，形成了与nasicon相关的晶体样品。电池参数计算表明，其沿两个系列的演变符合Na+被较小的Li+和较大的K+阳离子取代。用阻抗法对其电性能进行了研究。

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Synthesis, characterization and electrical properties of glass-ceramic samples of MIxNa4−xCoFe(PO4)3 (MI - Li, K) composition

The vitreous samples of M^I_xNa_4-xCoFe(PO₄)₃ (x = 0, 0.2 and 1.0, M^I - Li, K) composition were prepared by melt method. Formation of Nasicon-related crystalline samples was caused by the annealing at 600 °C. The cell parameters calculation showed that its evolution along two series agrees with the substitution of Na⁺ by smaller Li⁺ and bigger K⁺ cations. The electrical properties were investigated by the impedance method.

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International Conference on Oxide Materials for Electronic Engineering - fabrication, properties and applications (OMEE-2014)

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