Kazushi Hayashi, A. Hino, Hiroaki Tao, Mototaka Ochi, H. Goto, T. Kugimiya
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引用次数: 0
摘要
采用全光产率光谱(TPYS)研究了非晶in - ga - zn - o (a-IGZO)薄膜中氢相关缺陷态的演化过程。结果表明,氢化反应形成了距离真空4.3 eV左右的缺陷态。经300℃热处理后,TPYS光谱的起始点移至4.15 eV。随着退火温度的升高,缺陷态的光产率降低,表明氢和Zn从a-IGZO向外扩散。这些实验直接证明了a- igzo薄膜中氢的掺入导致了缺陷态的形成。
Evolution of hydrogen-related defect states in amorphous In-Ga-Zn-O analyzed by photoelectron emission yield experiments
Total photoyield spectroscopy (TPYS) was applied to investigate the evolution of hydrogen-related defect states in amorphous In-Ga-Zn-O (a-IGZO) thin films. It was found that the defect states located at around 4.3 eV from the vacuum level were formed as a result of hydrogenation. After thermal annealing at 300 °C, the onset of the TPYS spectra shifted to 4.15 eV. As the annealing temperature was increased, the photoyield from the defect states decreased, implying that there was outdiffusion of hydrogen with Zn from the a-IGZO. These experiments produced direct evidence which shows the formation of defect states as a result of hydrogen incorporation into the a-IGZO thin films.