{"title":"(乙二腈)四乙酸(EDTA)的X(N)螯合物的有氧光降解:对天然水体的影响。","authors":"H B Lockhart, R V Blakeley","doi":"10.1080/00139307509437453","DOIUrl":null,"url":null,"abstract":"<p><p>The behavior of several metal chelates [X(N)] of 1-14C-(ethylenedinitrilo) tetraacetic acid [EDTA] under irradiation from a wide spectrum Xenon arc lamp has been studied. In static tests at pH 4.5, chelates of Mn(II), Fe(II) and Co(II) photodegraded to give 14CO2 and CH2O. Chelates of Na(I), Mg(II), Ca(II), Ni(II), Cu(II), Zn(II), Cd(II), and Hg(II) did not exhibit any significant photodegradation as measured by 14CO2 evolution. It is concluded that the photodegradation of Fe(III)-EDTA by sunlight will prevent EDTA build up in natural waters.</p>","PeriodicalId":11979,"journal":{"name":"Environmental letters","volume":"9 1","pages":"19-31"},"PeriodicalIF":0.0000,"publicationDate":"1975-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1080/00139307509437453","citationCount":"30","resultStr":"{\"title\":\"Aerobic photodegradation of X(N) chelates of (ethylenedinitrilo)tetraacetic acid (EDTA): implications for natural waters.\",\"authors\":\"H B Lockhart, R V Blakeley\",\"doi\":\"10.1080/00139307509437453\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p><p>The behavior of several metal chelates [X(N)] of 1-14C-(ethylenedinitrilo) tetraacetic acid [EDTA] under irradiation from a wide spectrum Xenon arc lamp has been studied. In static tests at pH 4.5, chelates of Mn(II), Fe(II) and Co(II) photodegraded to give 14CO2 and CH2O. Chelates of Na(I), Mg(II), Ca(II), Ni(II), Cu(II), Zn(II), Cd(II), and Hg(II) did not exhibit any significant photodegradation as measured by 14CO2 evolution. It is concluded that the photodegradation of Fe(III)-EDTA by sunlight will prevent EDTA build up in natural waters.</p>\",\"PeriodicalId\":11979,\"journal\":{\"name\":\"Environmental letters\",\"volume\":\"9 1\",\"pages\":\"19-31\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1975-01-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://sci-hub-pdf.com/10.1080/00139307509437453\",\"citationCount\":\"30\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Environmental letters\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1080/00139307509437453\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Environmental letters","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1080/00139307509437453","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Aerobic photodegradation of X(N) chelates of (ethylenedinitrilo)tetraacetic acid (EDTA): implications for natural waters.
The behavior of several metal chelates [X(N)] of 1-14C-(ethylenedinitrilo) tetraacetic acid [EDTA] under irradiation from a wide spectrum Xenon arc lamp has been studied. In static tests at pH 4.5, chelates of Mn(II), Fe(II) and Co(II) photodegraded to give 14CO2 and CH2O. Chelates of Na(I), Mg(II), Ca(II), Ni(II), Cu(II), Zn(II), Cd(II), and Hg(II) did not exhibit any significant photodegradation as measured by 14CO2 evolution. It is concluded that the photodegradation of Fe(III)-EDTA by sunlight will prevent EDTA build up in natural waters.
求助内容：
应助结果提醒方式：
京公网安备 11010802042870号
