新型四氟苯液晶的铁电性质研究

Xian–Shan Wang, J. Wen
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引用次数: 0

摘要

利用正弦波绘制极化与电场的关系,结合光学偏光显微镜和差示扫描量热仪等常用方法,测定了液晶的铁电性。结果表明,以四氟联苯为分子核心结构的液晶具有较宽的铁电介相SmC*温度范围,4'-[(s)-2-甲基丁基羰基]苯基4-(4'-n-壬基氧基- 2,3,5,6 -四氟联苯-1-乙基)苯甲酯在60 ~ 170/spl℃范围内,极化率为8.9/spl次/10/sup -6/ C/m/sup 2/,居里点以下温度为10/spl℃时的倾斜角为9.2°。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Studies of ferroelectric properties of novel liquid crystals with tetrafluorophenylene
Plotting polarization versus electric field with sine waveform is used to determine the ferroelectricity of liquid crystals in conjunction with other usual methods as optical polarizing microscope and differential scanning calorimeter. Results show that the liquid crystal with the molecular core structure of tetrafluorobiphenylene has a rather wide temperature range of ferroelectric mesophase SmC*, and 4'-[(s)-2-methylbutoxycarbonyl] phenyl 4-(4'-n-nonyloxy-2, 3, 5, 6-tetrafluorobiphenyl-1-ethynyl) benzoate exhibits the range of about 110/spl deg/C from 60 to 170/spl deg/C, the polarization of 8.9/spl times/10/sup -6/ C/m/sup 2/ and the tilt angle of 9.2 degrees at temperature 10/spl deg/C below curie point.
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