枝状纤维型SBA-15 (DFSBA-15)吸附水溶液中的铅(II)

R. M. Mohd Zaki, H. D. Setiabudi, N. Kamarudin, B. Abdulkadir
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引用次数: 2

摘要

不可否认,环境中存在的重金属对生物是有害和有毒的,人类食物和饮料中存在的铅(II)会导致各种疾病。吸附作为污水处理的一种方法被广泛使用,有效的吸附性能取决于合适的吸附剂的选择。本研究制备了树枝状纤维型SBA-15 (DFSBA-15),并将其用于铅(Pb(II))的吸附。利用TEM、BET和FTIR表征了DFSBA-15的理化性质。表征分析证实了纤维形态的形成,中等的表面积和体积-OH。考察了接触时间(min)、吸附剂用量(g/L)、pH、初始浓度(mg/L)等因素对Pb(II)的吸附效果。当吸附剂投加量为1 g/L、pH为5、Pb(II)初始浓度为100 mg/L时,吸附时间为180 min,吸附效果为89.88%。拟二级反应类型和Langmuir等温线与实验数据拟合较好,R2≥0.9943,R2 = 0.9982。总之,DFSBA-15表现出优异的Pb(II)去除潜力。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Adsorption of Pb(II) from Aqueous Solution Using Dendritic Fibrous Type SBA-15 (DFSBA-15)
The presence of heavy metals in the environment is undeniably harmful and toxic to living things, where the presence of Pb(II) inside human foods and drinks results in various diseases. The use of adsorption as a method of wastewater treatment is widespread, and effective adsorption performance depends on appropriate adsorbent selection. In this research, dendritic fibrous type SBA-15 (DFSBA-15) was prepared and used for lead (Pb(II)) adsorption. The physicochemical properties of the DFSBA-15 were characterized using TEM, BET, and FTIR. The characterization analyses confirmed the formation of fibrous morphology, moderate surface area, and bulk -OH. Several factors, including contact time (min), adsorbent dosage (g/L), pH, and initial concentration (mg/L), were examined for Pb(II) adsorption. The best adsorption performance (89.88%) was attained at 180 min, 1 g/L of adsorbent dosage, pH 5, and 100 mg/L of Pb(II) initial concentration. Pseudo-second-order reaction type and Langmuir isotherm provided good fits to the experimental data, with R2 ≥ 0.9943 and R2 = 0.9982, respectively. In short, the DFSBA-15 exhibits great potential for excellent Pb(II) removal.
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