{"title":"用Rietveld方法分析Zn/sub - 4-x/Cd/sub -x/ Sb/sub - 3/化合物的结构参数比较","authors":"T. Souma, M. Ohtaki","doi":"10.1109/ICT.2005.1519973","DOIUrl":null,"url":null,"abstract":"A comparison of detailed structural parameters between the 3IS and Mayer models for the Zn/sub 4-x/Cd/sub x/Sb/sub 3/ system in the Zn-rich region has been successfully performed by the powder XRD study with the Rietveld method using 9 bulk crystals synthesized by vacuum casting method without annealing. The 3IS model gives a better fitting on the Rietveld analysis not only for the undoped Zn/sub 4/Sb/sub 3/ but also for the whole compositional range of the Zn-rich region of the Zn/sub 4-x/Cd/sub x/Sb/sub 3/ compounds. The purities and densities of the bulk crystals exceeded approximately 96 mass% and 95% of XRD density, respectively.","PeriodicalId":422400,"journal":{"name":"ICT 2005. 24th International Conference on Thermoelectrics, 2005.","volume":"72 1","pages":"0"},"PeriodicalIF":0.0000,"publicationDate":"2005-06-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Comparison of structural parameters for Zn/sub 4-x/Cd/sub x/Sb/sub 3/ compounds analyzed by the Rietveld method using two crystallographic models\",\"authors\":\"T. Souma, M. Ohtaki\",\"doi\":\"10.1109/ICT.2005.1519973\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"A comparison of detailed structural parameters between the 3IS and Mayer models for the Zn/sub 4-x/Cd/sub x/Sb/sub 3/ system in the Zn-rich region has been successfully performed by the powder XRD study with the Rietveld method using 9 bulk crystals synthesized by vacuum casting method without annealing. The 3IS model gives a better fitting on the Rietveld analysis not only for the undoped Zn/sub 4/Sb/sub 3/ but also for the whole compositional range of the Zn-rich region of the Zn/sub 4-x/Cd/sub x/Sb/sub 3/ compounds. The purities and densities of the bulk crystals exceeded approximately 96 mass% and 95% of XRD density, respectively.\",\"PeriodicalId\":422400,\"journal\":{\"name\":\"ICT 2005. 24th International Conference on Thermoelectrics, 2005.\",\"volume\":\"72 1\",\"pages\":\"0\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2005-06-19\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"ICT 2005. 24th International Conference on Thermoelectrics, 2005.\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1109/ICT.2005.1519973\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"ICT 2005. 24th International Conference on Thermoelectrics, 2005.","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1109/ICT.2005.1519973","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Comparison of structural parameters for Zn/sub 4-x/Cd/sub x/Sb/sub 3/ compounds analyzed by the Rietveld method using two crystallographic models
A comparison of detailed structural parameters between the 3IS and Mayer models for the Zn/sub 4-x/Cd/sub x/Sb/sub 3/ system in the Zn-rich region has been successfully performed by the powder XRD study with the Rietveld method using 9 bulk crystals synthesized by vacuum casting method without annealing. The 3IS model gives a better fitting on the Rietveld analysis not only for the undoped Zn/sub 4/Sb/sub 3/ but also for the whole compositional range of the Zn-rich region of the Zn/sub 4-x/Cd/sub x/Sb/sub 3/ compounds. The purities and densities of the bulk crystals exceeded approximately 96 mass% and 95% of XRD density, respectively.
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