水的Rydberg光谱的旋转分析

Laser Chemistry Pub Date : 1900-01-01 DOI:10.1155/LC.11.253

M. Child, R. D. Gilbert, C. Jungen

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引用次数: 3

摘要

讨论了两种用于分析H2O和D2O的nd←1b1 Rydberg光谱的旋转分析技术——用于室温3d←1b1簇的科里奥利耦合不对称顶部模型，以及将多通道量子缺陷理论扩展到不对称顶部，并将其应用于最近收敛到H2O(100)振动能级的nd←1b1系列的射流冷却光离光谱

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Rotational Analysis of the Rydberg Spectrum of Water

Two techniques for rotational analysis of the nd←1b1 Rydberg spectra of H2O and D2O are discussed—a Coriolis coupled asymmetric top model for the room temperature 3d←1b1 cluster, and an extension of multichannel quantum defect theory to asymmetric tops, which is applied to recent jet cooled photoionization spectra of the nd←1b1 series converging to the (100) vibrational levels of H2O

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来源期刊

Laser Chemistry

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