铪对NiAl和Ni3Al合金高温氧化的影响

R. Swadźba, Instytut Metalurgii Żelaza im. St. Staszica
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引用次数: 2

摘要

本文的研究结果涉及用活性元素对NiAl和Ni3Al合金进行改性,以提高其高温抗氧化性。文献数据表明,在1100-1150°C范围内,即使微量添加Hf也能显著提高铝化物涂层的抗氧化性,但其影响的确切机制尚不清楚。为了确定不同Hf添加量对铝化物涂层高温氧化的影响,在1150℃下对模型NiAl和Ni3Al合金进行了循环氧化试验,Hf添加量从0.25 wt.%到1.5 wt.%不等。采用高分辨率电子显微镜和化学成分分析技术,详细表征了高温氧化过程中形成的纳米级氧化层中Hf对其亚结构、化学和相组成的影响。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
INFLUENCE OF HAFNIUM ON HIGH TEMPERATURE OXIDATION OF NiAl AND Ni3Al ALLOYS
The results presented in this paper concern the modification of NiAl and Ni3Al alloys with reactive elements that increase their high temperature oxidation resistance. Literature data indicate that even trace additions of Hf to aluminide coatings significantly improve the resistance to oxidation in the range of 1100–1150°C, however the exact mechanism of its influence is not yet known. In order to determine the influence of various additions of Hf on high temperature oxidation of aluminide coatings, cyclic oxidation tests were performed at 1150°C of model NiAl and Ni3Al alloys with different Hf additions – from 0.25 wt.% to 1.5 wt.%. High resolution electron microscopy, as well as chemical composition analysis techniques, were applied to perform a detailed characterisation of the influence of Hf on the substructure, chemical and phase composition in the nano scale of oxide scales formed during high temperature oxidation.
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