Yating Li, Zuhao Yu, Prof. Jianhang Huang, Prof. Yonggang Wang, Prof. Yongyao Xia
{"title":"锌水电池固体电解质界面相的构建","authors":"Yating Li, Zuhao Yu, Prof. Jianhang Huang, Prof. Yonggang Wang, Prof. Yongyao Xia","doi":"10.1002/ange.202309957","DOIUrl":null,"url":null,"abstract":"<p>Problems of zinc anode including dendrite and hydrogen evolution seriously degrade the performance of zinc batteries. Solid electrolyte interphase (SEI), which plays a key role in achieving high reversibility of lithium anode in aprotic organic solvent, is also beneficial to performance improvement of zinc anode in aqueous electrolyte. However, various studies about interphase for zinc electrode is quite fragmented, and lack of deep understanding on root causes or general design rules for SEI construction. And water molecules with high reactivity brings serious challenge to the effective SEI construction. Here, we reviewed the brief development history of zinc batteries firstly, then summarized the approaches to construct SEI in aqueous electrolyte. Furthermore, the formation mechanisms behind approaches are systematically analyzed, together with discussion on the SEI components and evaluation on electrochemical performance of zinc anode with various types of SEI. Meanwhile, the challenge between lab and industrialization are also discussed.</p>","PeriodicalId":7803,"journal":{"name":"Angewandte Chemie","volume":null,"pages":null},"PeriodicalIF":0.0000,"publicationDate":"2023-08-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Constructing Solid Electrolyte Interphase for Aqueous Zinc Batteries\",\"authors\":\"Yating Li, Zuhao Yu, Prof. Jianhang Huang, Prof. Yonggang Wang, Prof. Yongyao Xia\",\"doi\":\"10.1002/ange.202309957\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>Problems of zinc anode including dendrite and hydrogen evolution seriously degrade the performance of zinc batteries. Solid electrolyte interphase (SEI), which plays a key role in achieving high reversibility of lithium anode in aprotic organic solvent, is also beneficial to performance improvement of zinc anode in aqueous electrolyte. However, various studies about interphase for zinc electrode is quite fragmented, and lack of deep understanding on root causes or general design rules for SEI construction. And water molecules with high reactivity brings serious challenge to the effective SEI construction. Here, we reviewed the brief development history of zinc batteries firstly, then summarized the approaches to construct SEI in aqueous electrolyte. Furthermore, the formation mechanisms behind approaches are systematically analyzed, together with discussion on the SEI components and evaluation on electrochemical performance of zinc anode with various types of SEI. Meanwhile, the challenge between lab and industrialization are also discussed.</p>\",\"PeriodicalId\":7803,\"journal\":{\"name\":\"Angewandte Chemie\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2023-08-19\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Angewandte Chemie\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://onlinelibrary.wiley.com/doi/10.1002/ange.202309957\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Angewandte Chemie","FirstCategoryId":"1085","ListUrlMain":"https://onlinelibrary.wiley.com/doi/10.1002/ange.202309957","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Constructing Solid Electrolyte Interphase for Aqueous Zinc Batteries
Problems of zinc anode including dendrite and hydrogen evolution seriously degrade the performance of zinc batteries. Solid electrolyte interphase (SEI), which plays a key role in achieving high reversibility of lithium anode in aprotic organic solvent, is also beneficial to performance improvement of zinc anode in aqueous electrolyte. However, various studies about interphase for zinc electrode is quite fragmented, and lack of deep understanding on root causes or general design rules for SEI construction. And water molecules with high reactivity brings serious challenge to the effective SEI construction. Here, we reviewed the brief development history of zinc batteries firstly, then summarized the approaches to construct SEI in aqueous electrolyte. Furthermore, the formation mechanisms behind approaches are systematically analyzed, together with discussion on the SEI components and evaluation on electrochemical performance of zinc anode with various types of SEI. Meanwhile, the challenge between lab and industrialization are also discussed.