Photocatalytic and Electrochemical Borylation and Silylation Reactions

IF 7 2区化学 Q1 CHEMISTRY, MULTIDISCIPLINARY

Chemical record Pub Date : 2023-06-26 DOI:10.1002/tcr.202300172

Tony Biremond, Dr. Margaux Riomet, Prof. Dr. Philippe Jubault, Prof. Dr. Thomas Poisson

引用次数: 0

Abstract

Due to their high versatility borylated and silylated compounds are inevitable synthons for organic chemists. To escape the classical hydroboration/hydrosilylation paradigm, chemists turned their attention to more modern and green methods such as photoredox chemistry and electrosynthesis. This account focuses on novel methods for the generation of boryl and silyl radicals to forge C−B and C−Si bonds from our group.

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光催化和电化学硼化和硅化反应。

由于它们的高通用性，硼化和硅化化合物是有机化学家不可避免的合成物。为了摆脱经典的硼氢化/硅氢化范式，化学家们将注意力转向更现代和绿色的方法，如光氧化还原化学和电合成。本帐户侧重于新方法的产生硼基和硅基自由基，以锻造C-B和C-Si键从我们的组。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

Chemical record 化学-化学综合

CiteScore

11.00

自引率

3.00%

发文量

188

审稿时长

>12 weeks

期刊介绍： The Chemical Record (TCR) is a "highlights" journal publishing timely and critical overviews of new developments at the cutting edge of chemistry of interest to a wide audience of chemists (2013 journal impact factor: 5.577). The scope of published reviews includes all areas related to physical chemistry, analytical chemistry, inorganic chemistry, organic chemistry, polymer chemistry, materials chemistry, bioorganic chemistry, biochemistry, biotechnology and medicinal chemistry as well as interdisciplinary fields. TCR provides carefully selected highlight papers by leading researchers that introduce the author''s own experimental and theoretical results in a framework designed to establish perspectives with earlier and contemporary work and provide a critical review of the present state of the subject. The articles are intended to present concise evaluations of current trends in chemistry research to help chemists gain useful insights into fields outside their specialization and provide experts with summaries of recent key developments.