Effect of humic compost on the adsorption of cadmium (II) in aqueous medium.

IF 16.4 1区 化学 Q1 CHEMISTRY, MULTIDISCIPLINARY
Accounts of Chemical Research Pub Date : 2023-01-01 Epub Date: 2023-04-24 DOI:10.1080/10934529.2023.2204798
Daniele Cristina Hass Seremeta, Cleber Pinto da Silva, Sandro Xavier de Campos
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引用次数: 0

Abstract

The humic compost obtained from the treatment of tobacco from smuggled cigarettes (SCT) and industrial sewage sludge (ISS) was evaluated as adsorbent for Cd (II) in aqueous solution, for possible decontamination of water resources. Optimum conditions were found at pH 5 and a 3 g/L adsorbent concentration, which presented 92% Cd (II) removal and maximum adsorption capacity of 28.546 mg/g. The pseudo-second-order kinetic model presented the best fit, pointing 120 min as the time needed to attain a steady state. FTIR and EDX results suggest the formation of coordinated Cd (II) bonds by functional groups between the compost and the solution. The results obtained in real samples showed that, even under different environmental conditions, the Cd (II) adsorption varied between 80.05 and 91.61%. The results indicated that the compost evaluated can be used for remediation of Cd (II)-contaminated water resources.

腐殖质堆肥对水介质中镉 (II) 吸附的影响。
对从处理走私烟烟草(SCT)和工业污水污泥(ISS)中获得的腐殖堆肥作为水溶液中镉(II)的吸附剂进行了评估,以便对水资源进行净化。最佳条件是 pH 值为 5,吸附剂浓度为 3 g/L,镉(II)去除率为 92%,最大吸附容量为 28.546 mg/g。伪二阶动力学模型的拟合效果最好,达到稳定状态所需的时间为 120 分钟。傅立叶变换红外光谱(FTIR)和电离辐射观察(EDX)结果表明,堆肥和溶液之间的官能团形成了配位镉(II)键。实际样品的结果表明,即使在不同的环境条件下,镉(II)的吸附率也在 80.05% 到 91.61% 之间。结果表明,所评估的堆肥可用于修复受镉 (II) 污染的水资源。
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来源期刊
Accounts of Chemical Research
Accounts of Chemical Research 化学-化学综合
CiteScore
31.40
自引率
1.10%
发文量
312
审稿时长
2 months
期刊介绍: Accounts of Chemical Research presents short, concise and critical articles offering easy-to-read overviews of basic research and applications in all areas of chemistry and biochemistry. These short reviews focus on research from the author’s own laboratory and are designed to teach the reader about a research project. In addition, Accounts of Chemical Research publishes commentaries that give an informed opinion on a current research problem. Special Issues online are devoted to a single topic of unusual activity and significance. Accounts of Chemical Research replaces the traditional article abstract with an article "Conspectus." These entries synopsize the research affording the reader a closer look at the content and significance of an article. Through this provision of a more detailed description of the article contents, the Conspectus enhances the article's discoverability by search engines and the exposure for the research.
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