Stabilization of the NOP ferroelectric phase in potassium nitrate–barium titanate ferroelectric composites

IF 0.2 Q4 PHYSICS, MULTIDISCIPLINARY
Olga A. Alekseeva , Aleksandr А. Naberezhnov , Elena V. Stukova , Valeriy G. Simkin
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引用次数: 0

Abstract

The study of temperature evolution of KNO3 (NOP) structure in ferroelectric (1−x)KNO3 + (x)BaTiO3 composites with BaTiO3 concentrations х = 0.25, 0.50 and 0.53 has been carried out on cooling with the use of the neutron diffraction technique. It was shown that, on cooling, the phase transition temperature (Tc) from the high-temperature paraelectric phase into the ferroelectric one did not depend on barium titanate concentration and practically coincided with Tc for pure NOP. Moreover, it was found that the admixture of BaTiO3 essentially enlarged the temperature range of NOP ferroelectric phase stability in the composites with BaTiO3 concentrations x = 0.25 and 0.50. The suppression of the ferroelectric phase was observed for the composite with x = 0.53.

硝酸钾-钛酸钡铁电复合材料中NOP铁电相的稳定性
利用中子衍射技术研究了铁电(1−x)KNO3 + (x)BaTiO3复合材料(BaTiO3浓度为 = ,0.25,0.50和0.53)中KNO3 (NOP)结构的温度演化。结果表明,在冷却时,从高温准电相到铁电相的相变温度(Tc)与钛酸钡浓度无关,与纯NOP的Tc基本一致。此外,在BaTiO3浓度为x = 0.25和0.50的复合材料中,BaTiO3的掺入实质上扩大了NOP铁电相稳定性的温度范围。当x = = 0.53时,铁电相被抑制。
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