Synthesis of polymethylbenzenes by methanol conversion on different types of zeolite

A.L. Lapidus, B.V. Kuklin, A.Yu. Krylova, S.D. Sominskii, Kh.M. Minachev
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Abstract

  • 1.

    1. The conversion of methanol (P 0·1 MPa, t 360°C, volumetric flowrate 0·3 hr−1) H- and La-formsof TsVM, mordenite, and dealuminized mordenite zeolites has been studied.

  • 2.

    2. It has been established that the introduction of lanthanum into a mordenite-type zeolite by means of ion exchange leads to an increase in its selectivity in relation to the formation of penta- and hexamethylbenzenes.

不同类型沸石上甲醇转化合成多甲基苯
1.1. 研究了甲醇(p0.1 MPa,温度360℃,体积流量0.3 hr−1)H-和la -形式在TsVM、丝光沸石和脱铝丝光沸石中的转化。已经确定,通过离子交换将镧引入丝光沸石型沸石中,导致其选择性的增加,这与五甲基苯和六甲基苯的形成有关。
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