Comparison of Optical Properties of Porphyrin Dispersed Polyimide and Porphyrin Incorporated Polyimide into the Main Chain

Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals Pub Date : 2001-10-01 DOI:10.1080/10587250108024741

Hooi-Sung Kim, T. Heo, Mi-Ra Kim, C. Ha, Jin-Kook Lee

引用次数: 1

Abstract

Abstract Optical properties of polyimide film with dispersed metalloporphyrin (ZnTPDPI) and those of polyimide film containing tetraphenyl-porphyrinzinc in polymer backbone (POTPPI) were compared. For ZnTPDPI, the increase of the content of ZnTPP in PI film exhibited the increase of absorption and emission. POTPPI showed higher emission and absorption than ZnTPDPI. Relative fluorescence quantum yield of POTPPI was 0.218, while that of ZnTPDPI was 0.125.

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卟啉分散聚酰亚胺与卟啉结合聚酰亚胺主链的光学性质比较

摘要比较了分散金属卟啉(ZnTPDPI)聚酰亚胺薄膜和聚合物骨架中含四苯基卟啉锌(POTPPI)聚酰亚胺薄膜的光学性能。对于ZnTPDPI，随着薄膜中ZnTPP含量的增加，其吸收和发射均增加。POTPPI的发射和吸收均高于ZnTPDPI。POTPPI相对荧光量子产率为0.218,ZnTPDPI相对荧光量子产率为0.125。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals

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