Monolayer and Langmuir–Blodgett films of amphiphilic complexes with 8-hydroxyquinoline

Jian-Ming Ouyang
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引用次数: 2

Abstract

A series of amphiphilic complexes of N-octadecyl-8-hydroxy-2-quinoline carboxamide, M(HO)2 (M=Mg, Ca, Mn, Ni, Zn, Pb), form a stable monolayer on a pure water subphase and can be easily fabricated as fairly stable uniform LB films. Absorption spectra and low-angle X-ray diffraction measurements showed that these LB films had good homogeneity and were Y-type bilayer films. From the position of the Bragg peaks, a thickness of ca. 5.38∼5.63 nm per bilayer were obtained. X-ray photoelectron spectroscopy analysis reveals a M : C : N ratio in the LB films consistent with the M(HO)2 on stoichiometry. These LB films exhibit intense fluorescence and may be used as emitting material of electroluminescent devices.

8-羟基喹啉两亲配合物的单层膜和Langmuir-Blodgett膜
一系列n -十八烷基-8-羟基-2-喹啉羧酰胺两亲性配合物M(HO)2 (M=Mg, Ca, Mn, Ni, Zn, Pb)在纯水亚相上形成稳定的单层,可以很容易地制备成相当稳定的均匀LB膜。吸收光谱和低角x射线衍射测量表明,LB膜具有良好的均匀性,为y型双层膜。从布拉格峰的位置,得到了每双分子层约5.38 ~ 5.63 nm的厚度。x射线光电子能谱分析表明,LB膜的M: C: N比值与M(HO)2的化学计量值一致。这些LB薄膜表现出强烈的荧光,可用作电致发光器件的发射材料。
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