Transition Metal-free Epoxidation of Alkenes Based on the Existence of (2- hydroxypropyl)-β-CD

The Open Chemical Engineering Journal Pub Date : 2015-04-17 DOI:10.2174/1874123101509010020

Shi Dongpo, Yin Xianqing, Zheng Yan-cheng, Chen Wu, Fu Jiaxin, Ren Zhaohua

引用次数: 0

Abstract

A green, efficient epoxidation of alkenes with hydrogen peroxide (H2O2) and sodium bicarbonate (NaHCO3) catalyzed by (2-hydroxypropyl)--cyclodextrin (2-hp--CD) in aqueous solution has been investigated in detail. A range of alkenes were epoxidized at ambient temperature with high yields.

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基于(2-羟丙基)-β- cd的烯烃过渡无金属环氧化反应

研究了在(2-羟丙基)--环糊精(2-hp-- cd)的催化下，烯烃与过氧化氢(H2O2)和碳酸氢钠(NaHCO3)在水溶液中的绿色高效环氧化反应。在常温下对一系列烯烃进行了高收率环氧化。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

The Open Chemical Engineering Journal

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