Lead tetra-acetate oxidation of NN-dimethylglycine and its relevance to the biosynthesis of the pyrrolidine ring of nicotine

E. Leete
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Abstract

A degradative sequence which has been used to determine the distribution of radioactivity in the pyrrolidine of nicotine involves, as one of the steps, the oxidation of NN-dimethylglycine with lead tetra-acetate; the formaldehyde produced in this reaction, formerly thought to originate entirely from C-2, has been shown to be derived in appreciable amounts from the N-methyl groups.
n -二甲基甘氨酸的四乙酸铅氧化及其与尼古丁吡咯烷环生物合成的关系
已用于测定尼古丁吡咯烷中放射性分布的降解序列包括:四乙酸铅氧化nn -二甲基甘氨酸;在这个反应中产生的甲醛,以前被认为完全来源于C-2,已经证明有相当数量的甲醛来源于n -甲基。
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